The Effect of Taro Tuber Starch (Colocasia esculenta (L.) schott) Addition to Characteristic of Biodegradable Plastic with PVA Polymer and Calcium Carbonate (CaCO3) Filler

Endah Saraswati, Intan Syahbanu, Adhitiyawarman Adhitiyawarman
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Abstract

The preparation of biodegradable plastics based on polyvinyl alcohol (PVA)-taro starch as an alternative to synthetic plastics has been conducted. The aim of this research was to identify the effect of taro starch composition on the production of biodegradable plastic and their characteristics in an aquatic environment. The solution casting method was used to produce biodegradable plastic. PVA was dissolved in hot distilled water, and taro starch (0; 0.5; 1.5; 2.5; and 3.5 g) was dissolved in another chamber filled with distilled water, glycerol and citric acid. Both solutions were mixed together and CaCO3 was then added. The mixture was casted on acrylic plates while biodegradable plastic without starch was used as a control. Characteristic of Biodegradable plastic and it’s properties were examined by Fourier Transform Infra Red (FTIR), water uptake, and moisture absorption test. While the biodegrability of the sample were tested in river water media in the laboratory. The results showed that the wave number at 1698-1712 cm-1, indicating that the cross-linking between PVA and the starch occured. Water uptake and moisture absorption tests showed that all of the biodegradable plastic varieties produced were hydrophilic. The biodegradation test showed that the largest degree of decomposition was reached by the PVA-starch 3.5 g variety which was 80.33%. Thus, the more starch on biodegradable plastic, the more biodegradation achieved.
芋淀粉(Colocasia esculenta(L.)schott)的添加对PVA聚合物和碳酸钙(CaCO3)填料生物降解塑料性能的影响
以聚乙烯醇(PVA)-芋头淀粉作为合成塑料的替代品,制备了可生物降解塑料。本研究的目的是确定芋头淀粉成分对生产可生物降解塑料的影响及其在水生环境中的特性。采用溶液浇铸法生产生物可降解塑料。将PVA溶解在热蒸馏水中,并将芋头淀粉(0;0.5;1.5;2.5;和3.5g)溶解在另一个充满蒸馏水、甘油和柠檬酸的腔室中。将两种溶液混合在一起,然后加入CaCO3。将混合物浇铸在丙烯酸板上,同时使用不含淀粉的可生物降解塑料作为对照。通过傅立叶变换红外光谱(FTIR)、吸水性和吸湿性测试,考察了可生物降解塑料的特性及其性能。同时在实验室对样品在河水介质中的生物降解性进行了测试。结果表明,在1698-1712cm-1处出现波数,表明PVA与淀粉发生交联。吸水和吸湿测试表明,生产的所有可生物降解塑料品种都是亲水性的。生物降解试验表明,PVA淀粉3.5g品种的降解率最高,为80.33%。因此,可生物降解塑料上的淀粉越多,生物降解效果越好。
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