Preparation and Characterization of Nanostructured Titania-coated Silica Microsphere Membranes with Simultaneous Photo-catalytic and Separation Applications for Water Treatment

Abstract

In this research, the nanostructured titania-coated silica microsphere (NTCSM) membrane consisting of titania-silica core-shell particles on α–alumina substrate was prepared by dip-coating method. The silica microspheres were synthesized by the Stöber method, and the nanostructured titania shell was obtained from a polymeric sol. Then, the prepared core-shell particles were deposited on alumina substrates. The samples were characterized by DLS, TG-DTA, XRD, FTIR and SEM. The photo-catalytic activity of the NTCSM membranes was evaluated using photo-degradation of methyl orange solution by UV–visible spectrophotometer. In addition, physical separation capability was investigated by filtration experiment based on methyl orange removal from aqueous solution using a membrane setup. The mean particle size of silica microspheres was determined to be around 650 nm, which increased to about 800nm by the deposition of titania nano-particles. After 60 min of UV-irradiation, the dye removal efficiency was determined to be 80% by the membrane. By coupling separation process with photo-catalytic technique, the removal efficiency was improved up to 97%. Thus, the NTCSM membranes showed simultaneous photo-degradation and separation capabilities for dye removal from water.