{"title":"Application Research on Pd-Co-Ti Catalyst for Purifying CO in Flue Gas of Hot-blast Stove in Steel Rolling Mill","authors":"Jian-dong Cai, Zehui Yu, Junda He, Jian Li","doi":"10.13052/spee1048-5236.4048","DOIUrl":null,"url":null,"abstract":"The Pd-Co-Ti catalyst was successfully prepared by the method of impregnation-precipitation-ball milling. The structure and redox properties of Pd-Co-Ti catalyst was investigated by N22 desorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and H22-TPR. The results show that the Pd-Co-Ti catalyst has a large specific surface area and a rich pore structure, and there are Co33O44 and anatase TiO22 crystals in the catalyst. The synergistic effect of Pd and Co improves the redox ability of Pd-Co-Ti catalyst. The catalyst is used to treat CO in the flue gas of rolling mills. It runs for 168 hours at a space velocity of 30,000 cm33/(g⋅⋅h) and a temperature of 280∘∘C, and the CO removal rate is basically maintained at more than 90%. The ratio of inlet CO content and O22 content affects the catalyst CO removal efficiency. When the ratio is greater than 0.5, the CO removal efficiency has a downward trend. The results of this study are of great significance to the practical application of CO oxidation technology.","PeriodicalId":35712,"journal":{"name":"Strategic Planning for Energy and the Environment","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Strategic Planning for Energy and the Environment","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.13052/spee1048-5236.4048","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Environmental Science","Score":null,"Total":0}
引用次数: 0
Abstract
The Pd-Co-Ti catalyst was successfully prepared by the method of impregnation-precipitation-ball milling. The structure and redox properties of Pd-Co-Ti catalyst was investigated by N22 desorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and H22-TPR. The results show that the Pd-Co-Ti catalyst has a large specific surface area and a rich pore structure, and there are Co33O44 and anatase TiO22 crystals in the catalyst. The synergistic effect of Pd and Co improves the redox ability of Pd-Co-Ti catalyst. The catalyst is used to treat CO in the flue gas of rolling mills. It runs for 168 hours at a space velocity of 30,000 cm33/(g⋅⋅h) and a temperature of 280∘∘C, and the CO removal rate is basically maintained at more than 90%. The ratio of inlet CO content and O22 content affects the catalyst CO removal efficiency. When the ratio is greater than 0.5, the CO removal efficiency has a downward trend. The results of this study are of great significance to the practical application of CO oxidation technology.