Analysis of the influence of different types of cement on the resistance to attack by sulfates

Daniel Schiavini, W. Mazer, Elizamary Otto Ferreira, J. M. Fonseca
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Abstract

The diversity of the types of cement manufactured, driven by the extensive use of additions, has given cementitious composites properties that can directly interfere in the durability and useful life of concrete. Considering the interaction of sulfate ions with cement hydration products, in order to understand it becomes essential for the proper choice of materials in order to protect the structures from this aggressor agent. In order to verify the influence of the choice of cement type on the resistance to attack by sulfates, this article analyzes the compressive strength; sulfate content, electron microscopy and energy dispersive spectroscopy of mortars made with cements CP II-F-32, CP IV-32 and CP V-ARI submitted to calcium, sodium and magnesium sulfate solutions for 4 months. The specimens exposed to calcium and sodium sulfate solutions showed increased compressive strength at early ages due to the formation of ettringite in the pores. On the other hand, CP II-F-32 cement showed the greatest deterioration due to magnesium sulfate attack.
不同类型水泥对硫酸盐侵蚀性能的影响分析
由于添加剂的广泛使用,所生产的水泥类型的多样性赋予了水泥基复合材料的特性,这些特性会直接影响混凝土的耐久性和使用寿命。考虑到硫酸根离子与水泥水化产物的相互作用,为了理解,正确选择材料以保护结构免受这种侵蚀剂的影响变得至关重要。为了验证水泥类型的选择对硫酸盐侵蚀性能的影响,本文分析了水泥的抗压强度;用水泥CP II-F-32、CP IV-32和CP V-ARI制成的砂浆在硫酸钙、钠和镁溶液中浸泡4个月后的硫酸盐含量、电子显微镜和能量色散光谱。暴露于钙和硫酸钠溶液中的试样在早期显示出由于孔隙中钙矾石的形成而增加的抗压强度。另一方面,CP II-F-32水泥由于硫酸镁侵蚀而表现出最大的劣化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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