{"title":"Tetraalkylammonium and phosphonium salt for asphaltene dispersion; experimental studies on interaction mechanisms","authors":"Shirin Baghersaei , Babak Mokhtari , Nahid Pourreza , Bahram Soltani Soulgani","doi":"10.1016/j.ejpe.2022.07.004","DOIUrl":null,"url":null,"abstract":"<div><p>Asphaltenes deposition is one of the most severe problems in the petroleum industry, imposing high costs on oil producer companies. The use of chemical dispersants reduces the risk of asphaltene deposition. For this purpose, a variety of chemicals with different structures and functional groups were designed and synthesized. Organic quaternary salts, such as ionic liquids, have been widely used to control asphaltene deposition over the last two decades, but the mechanism of their interaction with asphaltene has not been studied in detail. In this study, the interaction of ten commercial quaternary ammonium and phosphonium salts with asphaltene molecules was investigated using ultraviolet-visible (UV-Vis) spectroscopy. It was observed that the size, shape, and hydrophobicity of their cations or anions play an essential role in the dispersion of asphaltene aggregations. The results showed that the interaction of these quaternary salts is strongly influenced by the hydrophobic nature of the salt, and salts with more hydrophobic cations and anions, such as tetrabutylammonium iodide, tetrabutylammonium hexafluorophosphate, and cetyltrimethylammonium bromide, can better disperse asphaltene aggregations. The results also revealed that the role of anions such as iodide, and hexafluorophosphate in the dispersion of asphaltene aggregates is more important than cations. In addition, the results showed that except for tetramethylammonium bromide, the efficiency of the salts was increased with increasing concentration.</p></div>","PeriodicalId":11625,"journal":{"name":"Egyptian Journal of Petroleum","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1110062122000514/pdfft?md5=e6d30ea0208b8a0f189b9b81abdc8dd4&pid=1-s2.0-S1110062122000514-main.pdf","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Egyptian Journal of Petroleum","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1110062122000514","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Earth and Planetary Sciences","Score":null,"Total":0}
引用次数: 3
Abstract
Asphaltenes deposition is one of the most severe problems in the petroleum industry, imposing high costs on oil producer companies. The use of chemical dispersants reduces the risk of asphaltene deposition. For this purpose, a variety of chemicals with different structures and functional groups were designed and synthesized. Organic quaternary salts, such as ionic liquids, have been widely used to control asphaltene deposition over the last two decades, but the mechanism of their interaction with asphaltene has not been studied in detail. In this study, the interaction of ten commercial quaternary ammonium and phosphonium salts with asphaltene molecules was investigated using ultraviolet-visible (UV-Vis) spectroscopy. It was observed that the size, shape, and hydrophobicity of their cations or anions play an essential role in the dispersion of asphaltene aggregations. The results showed that the interaction of these quaternary salts is strongly influenced by the hydrophobic nature of the salt, and salts with more hydrophobic cations and anions, such as tetrabutylammonium iodide, tetrabutylammonium hexafluorophosphate, and cetyltrimethylammonium bromide, can better disperse asphaltene aggregations. The results also revealed that the role of anions such as iodide, and hexafluorophosphate in the dispersion of asphaltene aggregates is more important than cations. In addition, the results showed that except for tetramethylammonium bromide, the efficiency of the salts was increased with increasing concentration.
期刊介绍：
Egyptian Journal of Petroleum is addressed to the fields of crude oil, natural gas, energy and related subjects. Its objective is to serve as a forum for research and development covering the following areas: • Sedimentation and petroleum exploration. • Production. • Analysis and testing. • Chemistry and technology of petroleum and natural gas. • Refining and processing. • Catalysis. • Applications and petrochemicals. It also publishes original research papers and reviews in areas relating to synthetic fuels and lubricants - pollution - corrosion - alternate sources of energy - gasification, liquefaction and geology of coal - tar sands and oil shale - biomass as a source of renewable energy. To meet with these requirements the Egyptian Journal of Petroleum welcomes manuscripts and review papers reporting on the state-of-the-art in the aforementioned topics. The Egyptian Journal of Petroleum is also willing to publish the proceedings of petroleum and energy related conferences in a single volume form.
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