Synthesis, characterization and antioxidant property of nano-scaled metal complexes of triazine based hydroxy chalcone

IF 2.4 Q2 MULTIDISCIPLINARY SCIENCES

Smart Science Pub Date : 2022-05-18 DOI:10.1080/23080477.2022.2074660

A. Karthikeyan, J. Suresh, K. Balaji, S. Anandhakumar, A. Arun

引用次数: 1

Abstract

ABSTRACT In the present investigation, novel triazine-based chalcone ligand (1-(2,4-dihydroxyphenyl)-3-(4-((4-((4-nitrophenyl)amino)-6-phenoxy-1,3,5-triazin-2-yl)oxy)phenyl) prop-2-en-1-one) (DNPP) is synthesized and used in metal complexes synthesis which contains iron, copper, nickel, and zinc. 1H NMR and IR spectrum of DNPP confirms the formation of the product. UV-Visible spectrum shows a peak around 400–500 nm for d-d transition. SEM with EDX shows the metal complexes is in crystalline state with the size in the range of 20–50 nm. TGA analysis shows the synthesized compound is highly stable and the residue content confirms the presence of metal in the molecular structure. Antioxidant were found out to be <50 μg/ml. Graphical Abstract

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三嗪基羟基查尔酮纳米金属配合物的合成、表征及抗氧化性能

摘要本文合成了新型三嗪基查尔酮配体(1-(2,4-二羟基苯基)-3-(4-(4-硝基苯基)氨基)-6-苯氧基-1,3,5-三嗪-2-基氧基)苯基)丙基-2-烯-1-酮)(DNPP)，并将其用于含铁、铜、镍和锌的金属配合物的合成。DNPP的1H NMR和IR光谱证实了产物的形成。紫外可见光谱显示d-d跃迁在400-500 nm附近有一个峰。EDX扫描电镜显示金属配合物呈结晶态，尺寸在20 ~ 50 nm之间。TGA分析表明，合成的化合物具有较高的稳定性，残留物含量证实了金属在分子结构中的存在。抗氧化剂含量<50 μg/ml。图形抽象

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来源期刊

Smart Science Engineering-Engineering (all)

CiteScore

4.70

自引率

4.30%

发文量

期刊介绍： Smart Science (ISSN 2308-0477) is an international, peer-reviewed journal that publishes significant original scientific researches, and reviews and analyses of current research and science policy. We welcome submissions of high quality papers from all fields of science and from any source. Articles of an interdisciplinary nature are particularly welcomed. Smart Science aims to be among the top multidisciplinary journals covering a broad spectrum of smart topics in the fields of materials science, chemistry, physics, engineering, medicine, and biology. Smart Science is currently focusing on the topics of Smart Manufacturing (CPS, IoT and AI) for Industry 4.0, Smart Energy and Smart Chemistry and Materials. Other specific research areas covered by the journal include, but are not limited to: 1. Smart Science in the Future 2. Smart Manufacturing: -Cyber-Physical System (CPS) -Internet of Things (IoT) and Internet of Brain (IoB) -Artificial Intelligence -Smart Computing -Smart Design/Machine -Smart Sensing -Smart Information and Networks 3. Smart Energy and Thermal/Fluidic Science 4. Smart Chemistry and Materials