Ni/LaBO3 (B = Al, Cr, Fe) Catalysts for Steam Reforming of Methane (SRM): On the Interaction Between Ni and LaBO3 Perovskites with Differed Fine Structures

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL
Menghe Yang, Yingao Wang, Rui Zhang, Teng Liu, Lianghui Xia, Zijian Chen, Xiuzhong Fang, Xianglan Xu, Junwei Xu, Xiang Wang
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引用次数: 5

Abstract

With the target to fabricate more feasible catalysts for SRM to produce hydrogen, the interaction between Ni and LaBO3 (B = Al, Cr and Fe) perovskite supports with different B-sites has been explored. To avoid the formation of big Ni grains, the Ni loading is intentionally set as low as 2 wt%. XRD and Raman results revealed that the three LaBO3 supports are composed of pure perovskite phase, but have differed fine crystal structures. While LaFeO3 and LaCrO3 can be indexed to the orthorhombic perovskite phase, LaAlO3 can be indexed to the hexagonal phase. H2-TPR and XPS results have validated that NiO has varied interfacial interactions with the LaBO3 supports through partial electron transfer from the supports to Ni. As a consequence, the active metallic Ni surface areas are in the order of 2%Ni/LaAlO3 > 2%Ni/LaCrO3 > 2%Ni/LaFeO3, well consistent with the reaction performance. Furthermore, by varying the B-site element, the abundance of the active surface oxygen species (mainly O22−) is varied, obeying the sequence of 2%Ni/LaCrO3 > 2%Ni/LaAlO3 > 2%Ni/LaFeO3, well consistent with the anti-coking ability of the catalysts. It is discovered that the change of the fine crystal structure of LaBO3 supports can influence the SRM performance of the 2%Ni/LaBO3 catalysts evidently. The reaction performance of the catalysts is mainly determined by the active Ni surface area, but the anti-coking ability is majorly decided by the amount of active oxygen species.

甲烷蒸汽重整Ni/LaBO3 (B = Al, Cr, Fe)催化剂:Ni与不同细结构LaBO3钙钛矿的相互作用
以制备更可行的SRM制氢催化剂为目标,研究了Ni与不同B位的LaBO3 (B = Al, Cr和Fe)钙钛矿载体之间的相互作用。为了避免形成大的Ni晶粒,Ni的负荷量被有意地设定为低至2 wt%。XRD和Raman结果表明,三种LaBO3载体均由纯钙钛矿相组成,但具有不同的细晶结构。LaFeO3和LaCrO3可以被索引到正方晶钙钛矿相,LaAlO3可以被索引到六方晶钙钛矿相。H2-TPR和XPS结果验证了NiO与LaBO3载体通过部分电子从载体转移到Ni而发生不同的界面相互作用。结果表明,活性金属Ni表面积为2%Ni/LaAlO3 > 2%Ni/LaCrO3 > 2%Ni/LaFeO3,与反应性能一致。此外,随着b位元素的变化,活性表面氧(主要是O22−)的丰度也发生了变化,服从2%Ni/LaCrO3 > 2%Ni/LaAlO3 > 2%Ni/LaFeO3的顺序,与催化剂的抗结焦能力相吻合。结果表明,LaBO3载体细晶结构的改变对2%Ni/LaBO3催化剂的SRM性能有明显的影响。催化剂的反应性能主要由活性Ni的表面积决定,而抗结焦能力主要由活性氧的数量决定。
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来源期刊
Catalysis Surveys from Asia
Catalysis Surveys from Asia 化学-物理化学
CiteScore
4.80
自引率
0.00%
发文量
29
审稿时长
>12 weeks
期刊介绍: Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.
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