Solvothermal Synthesis of BiCuI5(phen)2, a Novel Metal–Organic Halobismuthate

IF 0.4 4区化学 Q4 CRYSTALLOGRAPHY

Journal of Chemical Crystallography Pub Date : 2022-03-16 DOI:10.1007/s10870-022-00932-6

Adrian T. Hines, Gregory Morrison, Mark D. Smith, Hans-Conrad zur Loye

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引用次数: 0

Abstract

Crystals of the title compound BiCuI₅(phen)₂ were synthesized solvothermally by reacting CuCl₂·2H₂O, Bi(NO₃)₃·5H₂O, NH₄I, and 1,10-phenanthroline in an ethanol/water solvent mixture. BiCuI₅(phen)₂ crystallizes in the monoclinic space group P2₁/n. The asymmetric unit consists of a [Bi₂I₁₀] iodobismuthate group and a [CuI(phen)₂] complex that are linked via a shared iodine. In this paper, we describe the synthesis and single crystal structure of the new metal–organic halobismuthate complex, BiCuI₅(phen)₂.

Graphical Abstract

X-ray diffraction quality single crystals of a novel metal–organic halobismuthate, BiCuI₅(phen)₂ were grown in water/ethanol solvent mixture at 120 °C and used for structure determination using single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P2₁/n.

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新型金属有机盐酸盐BiCuI5(phen)2的溶剂热合成

通过CuCl2·2H2O、Bi(NO3)3·5H2O、NH4I和1,10-菲罗啉在乙醇/水的溶剂混合物中反应，合成了标题化合物BiCuI5(phen)2的溶剂热晶体。BiCuI5(phen)2在单斜空间群P21/n中结晶。不对称单元由[Bi2I10]碘铋酸盐基团和[CuI(phen)2]配合物组成，它们通过共享碘连接。本文描述了新型金属-有机卤铋酸盐配合物BiCuI5(phen)2的合成及其单晶结构。摘要:在120℃的水/乙醇混合溶剂中生长出具有x射线衍射质量的新型金属-有机卤铋酸盐BiCuI5(phen)2单晶，并用单晶x射线衍射法测定其结构。该化合物在单斜空间群P21/n中结晶。

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来源期刊

Journal of Chemical Crystallography 化学-光谱学

CiteScore

1.50

自引率

12.50%

发文量

审稿时长

6.3 months

期刊介绍： Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.