Multinomial, Poisson and Gaussian statistics in count data analysis

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Jakob Lassa, Magnus Egede Boggild, P. Hedegaard, K. Lefmann
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引用次数: 6

Abstract

It is generally known that counting statistics is not correctly described by a Gaussian approximation. Nevertheless, in neutron scattering, it is common practice to apply this approximation to the counting statistics; also at low counting numbers. We show that the application of this approximation leads to skewed results not only for low-count features, such as background level estimation, but also for its estimation at double-digit count numbers. In effect, this approximation is shown to be imprecise on all levels of count. Instead, a Multinomial approach is introduced as well as a more standard Poisson method, which we compare with the Gaussian case. These two methods originate from a proper analysis of a multi-detector setup and a standard triple axis instrument. We devise a simple mathematical procedure to produce unbiased fits using the Multinomial distribution and demonstrate this method on synthetic and actual inelastic scattering data. We find that the Multinomial method provide almost unbiased results, and in some cases outperforms the Poisson statistics. Although significantly biased, the Gaussian approach is in general more robust in cases where the fitted model is not a true representation of reality. For this reason, a proper data analysis toolbox for low-count neutron scattering should therefore contain more than one model for counting statistics.
计数数据分析中的多项式、泊松和高斯统计
众所周知,计数统计不能用高斯近似来正确描述。然而,在中子散射中,通常的做法是将这种近似应用于计数统计;计数也很低。我们表明,这种近似的应用不仅会导致低计数特征(如背景水平估计)的结果偏斜,而且会导致双位数计数的估计结果偏斜。实际上,这种近似在所有计数级别上都是不精确的。相反,我们引入了一种多项式方法以及一种更标准的泊松方法,并将其与高斯情况进行比较。这两种方法源于对多探测器设置和标准三轴仪器的适当分析。我们设计了一种简单的数学方法来利用多项分布产生无偏拟合,并在合成和实际的非弹性散射数据上证明了这种方法。我们发现多项式方法提供了几乎无偏的结果,并且在某些情况下优于泊松统计。虽然有明显的偏差,但在拟合模型不能真实反映现实的情况下,高斯方法通常更健壮。因此,适当的低计数中子散射数据分析工具箱应包含一个以上的计数统计模型。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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