{"title":"Hydrogenation of 1,3-Pentadiene on Modified Pd-Containing Catalysts","authors":"L. M. Kustov, A. L. Tarasov, A. L. Kustov","doi":"10.1134/S2070050422040055","DOIUrl":null,"url":null,"abstract":"<p>The activity and selectivity of sulfidized and non- sulfidized palladium alumina supported catalysts in the hydrogenation of 1,3-pentadiene to pentenes is studied. Preliminary sulfidation of palladium catalysts substantially improves their selectivity toward olefins in a broad range of Н<sub>2</sub> : diene ratios (from 2.5 to 10). Samples activated in Н<sub>2</sub> at elevated temperatures display higher activity in diene hydrogenation. Palladium catalysts are more active at low temperatures of the reaction, but sulfidized Ni catalysts studied earlier are competitive with palladium ones in selectivity toward olefins and productivity, and are more selective in an excess of hydrogen. The modification of palladium with chromium, silver, or lithium improves the selectivity toward olefin.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"14 4","pages":"343 - 348"},"PeriodicalIF":0.7000,"publicationDate":"2022-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis in Industry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2070050422040055","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The activity and selectivity of sulfidized and non- sulfidized palladium alumina supported catalysts in the hydrogenation of 1,3-pentadiene to pentenes is studied. Preliminary sulfidation of palladium catalysts substantially improves their selectivity toward olefins in a broad range of Н2 : diene ratios (from 2.5 to 10). Samples activated in Н2 at elevated temperatures display higher activity in diene hydrogenation. Palladium catalysts are more active at low temperatures of the reaction, but sulfidized Ni catalysts studied earlier are competitive with palladium ones in selectivity toward olefins and productivity, and are more selective in an excess of hydrogen. The modification of palladium with chromium, silver, or lithium improves the selectivity toward olefin.
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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