{"title":"Preparation of phthalonitrile resins containing siloxane linkages with improved processability","authors":"Weihao Yin, X. Sang, Jinghui Dong, Zhen Chen, X. Chen","doi":"10.1177/09540083231162521","DOIUrl":null,"url":null,"abstract":"To improve the processability of biphenyl phthalonitrile resin, a flexible siloxane structure was introduced into the phthalonitrile monomer through molecular design, which was then blended with a biphenyl monomer to prepare phthalonitrile alloy resins. When the ratio of phthalonitrile monomer containing flexible siloxane to biphenyl phthalonitrile monomer was 1:1, the processing window widened from 58 to 110°C, as compared to that of biphenyl phthalonitrile. Due to the introduction of the biphenyl structure into the phthalonitrile alloy resins, the initial decomposition temperature of the silicon-containing phthalonitrile resin increased from 385 to 516°C. More importantly, the phthalonitrile alloy resin exhibited a high bending strength (66 MPa) and bending modulus (3762 MPa), indicating that it could be potentially applied as high temperature structural composite matrices. Furthermore, it provides a new strategy for processing phthalonitrile resins with a high melting point and narrow processing window.","PeriodicalId":12932,"journal":{"name":"High Performance Polymers","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2023-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Performance Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/09540083231162521","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 1
Abstract
To improve the processability of biphenyl phthalonitrile resin, a flexible siloxane structure was introduced into the phthalonitrile monomer through molecular design, which was then blended with a biphenyl monomer to prepare phthalonitrile alloy resins. When the ratio of phthalonitrile monomer containing flexible siloxane to biphenyl phthalonitrile monomer was 1:1, the processing window widened from 58 to 110°C, as compared to that of biphenyl phthalonitrile. Due to the introduction of the biphenyl structure into the phthalonitrile alloy resins, the initial decomposition temperature of the silicon-containing phthalonitrile resin increased from 385 to 516°C. More importantly, the phthalonitrile alloy resin exhibited a high bending strength (66 MPa) and bending modulus (3762 MPa), indicating that it could be potentially applied as high temperature structural composite matrices. Furthermore, it provides a new strategy for processing phthalonitrile resins with a high melting point and narrow processing window.
期刊介绍:
Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.