Effective Use of Biomass Wastes for Removing Hazardous Inorganic Ions from Aquatic Environment

K. Inoue
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Abstract

In recent years, pollution of water by various toxic materials has become serious all over the world especially in developing countries, caused by the development of industries in these countries. Among toxic materials, although mercury and lead are the most toxic, arsenic and fluorine are also toxic. Especially, pollution of underground water by arsenic in Bangladesh and India is well known. Although mercury and lead exist as cationic species in aquatic environments, majority of toxic inorganic materials exist as anionic species. For example, arsenic (III and V) exists oxo-anions such as arsenite (AsO3) and arsenate (AsO4), respectively. To avoid the pollution by these toxic elements, severe standards are required for effluents from industries in each country. For example, the typical standards in Japan are as follows; chromium (VI): 0.5, selenium: 0.1, arsenic: 0.1, flourine: 8 (unit; mg/dm3). To clear these standards, various techniques have been developed to date and some of them have been commercialized. The typical techniques are precipitation, electrochemical treatments, Donnan dialysis, ion exchange and adsorption. However, these conventional techniques are suffering from some drawbacks such as poor selectivity, high operation costs and so forth.
有效利用生物质废弃物去除水生环境中有害无机离子
近年来,由于发展中国家工业的发展,各种有毒物质对水的污染在世界范围内变得严重,特别是在发展中国家。在有毒物质中,虽然汞和铅的毒性最大,但砷和氟也有毒。特别是,孟加拉国和印度的地下水被砷污染是众所周知的。虽然汞和铅在水生环境中以阳离子形式存在,但大多数有毒无机物以阴离子形式存在。例如,砷(III)和砷(V)分别存在氧阴离子,如亚砷酸盐(AsO3)和砷酸盐(AsO4)。为了避免这些有毒元素的污染,每个国家都要求对工业废水制定严格的标准。例如,日本的典型标准如下:铬(VI): 0.5,硒:0.1,砷:0.1,氟:8(单位);毫克/ dm3)。为了清除这些标准,迄今为止已经开发了各种技术,其中一些已经商业化。典型的技术有沉淀、电化学处理、唐纳透析、离子交换和吸附。然而,这些传统技术存在着选择性差、操作成本高等缺点。
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