Vinylation of Betulin with Calcium Carbide

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Doklady Chemistry Pub Date : 2023-02-15 DOI:10.1134/S0012500822700124

Yu. V. Gyrdymova, K. S. Rodygin

引用次数: 0

Abstract

A method for the synthesis of betulin vinyl ether using calcium carbide as a source of acetylene has been proposed. Optimal conditions for synthesis of betulin mono- and divinyl ether have been selected. It has been found that the addition of alkali metal fluorides in an excess of calcium carbide promotes the formation of a divinylated product. Two-dimensional NMR spectroscopy proves the formation of monovinyl ether at the primary alcohol group.

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桦木素与电石的乙烯化反应

提出了一种以电石为乙炔源合成白桦脂乙烯醚的方法。选择了合成桦木素单醚和二乙烯基醚的最佳工艺条件。研究发现，在过量的电石中加入碱金属氟化物可促进二乙烯化产物的形成。二维核磁共振证实了在伯醇基上形成单乙烯基醚。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Doklady Chemistry 化学-化学综合

CiteScore

1.20

自引率

12.50%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.