Wear resistance of composite electrolytic coatings

M. Skyba, M. Stechyshyn, V. Oleksandrenko, N. Mashovets, Y. Bilyk
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Abstract

The article analyzes the influence of composite electrolytic coatings (CEC) on the wear resistance of structural steels. The issues of matrix selection and various combinations in composite coatings of different chemical elements and compounds are considered. Coatings based on chromium, nickel, iron, copper, cobalt and others are widely used in industry, but nickel-based composite coatings are the most widely used. Nickel is widely used as a matrix for CEC, because it has an affinity for most particles used as the second phase and easily forms a coating with them. These coatings are used for corrosion protection, increase of physical and mechanical and chemical parameters, increase of hardness and wear resistance, restoration of the sizes, giving to a surface of self-lubricating properties. Nickel-based coatings with SiC filler of various fractions from size 100/80 μm to nanoparticles smaller than 50 nm were investigated on the basis of the established installation for CEC application. Thus, SiC powders with the following sizes were used in the works: less than 50 nm - nanoparticles; M5; 28/20; 50/40; 100/80 μm. In the studies performed, 0.01… 0.02 g/l sodium lauryl sulfate was additionally introduced into the electrolyte, which promotes the incorporation of SiC particles into the coating and improves the conditions for building the Nickel matrix. Amorphous boron powders of about 1 μm size were also added to the silicon carbides as a filler, which is explained by the possibility of boron and nickel interaction during the subsequent heat treatment of the coating and obtaining new structures (solid solutions, eutectic, dispersion-hard alloys). It is of practical interest to study the possibility of improving the physical and mechanical properties of nickel-based CEC by introducing metals capable of heat treatment, interact with the metal matrix to form solid substitution solutions and chemical compounds (solid phases of implementation) and determine tribotechnical characteristics of these coatings.  
复合电解涂层的耐磨性
分析了复合电解质涂层(CEC)对结构钢耐磨性的影响。考虑了不同化学元素和化合物的复合涂层中基体的选择和各种组合的问题。基于铬、镍、铁、铜、钴等的涂层在工业中应用广泛,但镍基复合涂层的应用最为广泛。镍被广泛用作CEC的基质,因为它对用作第二相的大多数颗粒具有亲和力,并且很容易与它们形成涂层。这些涂层用于防腐、提高物理、机械和化学参数、提高硬度和耐磨性、恢复尺寸、赋予表面自润滑性能。在CEC应用的既定装置的基础上,研究了具有从尺寸100/80μm到小于50nm的纳米颗粒的不同分数的SiC填料的镍基涂层。因此,在工作中使用了以下尺寸的SiC粉末:小于50nm的纳米颗粒;M5;28/20;50/40;100/80μm。在进行的研究中,将0.01…0.02 g/l的十二烷基硫酸钠额外引入电解质中,这促进了SiC颗粒掺入涂层中,并改善了构建镍基体的条件。尺寸约为1μm的非晶硼粉末也被添加到碳化硅中作为填料,这可以通过在随后的涂层热处理过程中硼和镍相互作用的可能性来解释,并获得新的结构(固溶体、共晶、分散硬质合金)。研究通过引入能够热处理的金属来改善镍基CEC的物理和机械性能的可能性,与金属基体相互作用形成固体取代溶液和化合物(实施的固相),并确定这些涂层的摩擦学特性,具有实际意义。
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