Basic Ionic Liquid [Bmim]OH as Efficient Greener Medium for the Oxidation α-Hydroxy Ketone Compounds and Alcohols to Carbonyl Compounds with Potassium Permanganate

IF 0.7 Q4 CHEMISTRY, MULTIDISCIPLINARY

Orbital: The Electronic Journal of Chemistry Pub Date : 2022-12-26 DOI:10.17807/orbital.v14i4.15958

Baeamee Phungpis, P. Noppawan, Kanokkan Worawut

引用次数: 0

Abstract

In this work, a convenient and greener procedure for synthesizing 1,2-diarylethane-1,2-dione derivatives as well as the oxidation of primary and secondary alcohols was explored using an oxidizing agent (KMnO4) in a basic ionic liquid of 1-butyl-3-methylimidazolium hydroxide ([Bmim]OH) as greener medium. The selective oxidation of α-hydroxy ketone compounds together with primary and secondary alcohols in the presence of KMnO4 in [Bmim]OH afforded corresponding carbonyl compounds of 1,2-diarylethane-1,2-dione derivatives and aldehydes or ketones in high yields (85-97% and 83-97%, respectively). The reactions are mild, fast, and efficient. Moreover, KMnO4 in [Bmim]OH medium was easily recovered and reused for at least four additional reactions without significant loss of efficiency with a consistent yield of about 80%.

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碱性离子液体[Bmim]OH作为高锰酸钾氧化α-羟基酮和醇制羰基化合物的高效绿色介质

在本研究中，以1-丁基-3-甲基咪唑氢氧化物([Bmim]OH)碱性离子液体为绿色介质，探索了一种简便、环保的合成1,2-二乙烷-1,2-二酮衍生物以及氧化伯醇和仲醇的方法。在KMnO4存在下，α-羟基酮化合物与伯、仲醇在[Bmim]OH中选择性氧化，得到相应的1,2-二乙烷-1,2-二酮衍生物羰基化合物和醛或酮，收率高(分别为85-97%和83-97%)。这些反应温和、快速、有效。此外，KMnO4在[Bmim]OH介质中很容易回收并重复使用至少四个额外的反应，而没有明显的效率损失，产率稳定在80%左右。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Orbital: The Electronic Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.10

自引率

0.00%

发文量

审稿时长

10 weeks

期刊介绍： Orbital: The Electronic Journal of Chemistry is a quarterly scientific journal published by the Institute of Chemistry of the Universidade Federal de Mato Grosso do Sul, Brazil. Original contributions (in English) are welcome, which focus on all areas of Chemistry and their interfaces with Pharmacy, Biology, and Physics. Neither authors nor readers have to pay fees. The journal has an editorial team of scientists drawn from regions throughout Brazil and world, ensuring high standards for the texts published. The following categories are available for contributions: 1. Full papers 2. Reviews 3. Papers on Education 4. History of Chemistry 5. Short communications 6. Technical notes 7. Letters to the Editor The Orbital journal also publishes a number of special issues in addition to the regular ones. The central objectives of Orbital are threefold: (i) to provide the general scientific community (at regional, Brazilian, and worldwide levels) with a formal channel for the communication and dissemination of the Chemistry-related literature output by publishing original papers based on solid research and by reporting contributions which further knowledge in the field; (ii) to provide the community with open, free access to the full content of the journal, and (iii) to constitute a valuable channel for the dissemination of Chemistry-related investigations.