INFLUENCE OF UV RADIATION ON DIELECTRIC ABSORPTION AND DIELECTRIC STRENGTH OF HALLOYSITE NANOTUBES FILLED POLYETHYLENE COMPOSITES

P. Kadlec, R. Polanský
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Abstract

This paper deals with the evaluation of the amount of filler influence and the ultraviolet (UV) radiation influence on selected dielectric properties of the innovative type of composites. These composites consist of a linear low-density polyethylene matrix and a clay filler (with different filling levels) that contains halloysite nanotubes (HNT) primarily. The intended application of tested composites in the field of electrical engineering is in insulating systems of power cables. Attention is paid to the analysis of the behaviour of composites in their charging, which is caused by the connection with the direct voltage source. The volume resistivity and polarization indexes are determined based on this analysis. Analysis of charging based on the measurement of the current, which flows through the sample under constant applied voltage, is supplemented with the short evaluation of the material behaviour after the disconnecting of the voltage source and after the electrode shorting when the material is discharged. Furthermore, the measurement of dielectric strength under an alternating electric field as another key parameter of electrical insulating materials is determined. Results of analyses of absorption and resorption processes and the dielectric strength measurement of materials in the delivered state prove a significant effect of the filler percentage in the composite. Subsequently, markedly different values of selected parameters because of material exposure to UV radiation are also determined. Observed changes in dielectric properties caused by UV irradiation are supported by the analysis of the chemical structure of materials via Fourier transform infrared spectroscopy.
紫外线辐射对高岭土纳米管填充聚乙烯复合材料介电吸收和介电强度的影响
本文研究了填料用量对新型复合材料介电性能的影响及紫外辐射对其介电性能的影响。这些复合材料由线性低密度聚乙烯基体和主要含有高岭土纳米管(HNT)的粘土填料(具有不同的填充水平)组成。经测试的复合材料在电气工程领域的预期应用是电力电缆的绝缘系统。重点分析了复合材料在与直流电压源连接时的充电行为。在此基础上确定了体积电阻率和极化指标。充电分析基于恒定外加电压下流过样品的电流的测量,补充了对断开电压源后和材料放电时电极短路后材料行为的简短评估。在此基础上,确定了电绝缘材料在交变电场作用下的介电强度作为另一个关键参数的测量。对材料在输送状态下的吸收和再吸收过程进行了分析,并对材料的介电强度进行了测试,结果表明填料含量对复合材料有显著影响。随后,还确定了由于材料暴露于紫外线辐射而导致的选定参数的显着不同值。通过傅里叶变换红外光谱分析材料的化学结构,证实了紫外照射引起的介电性能变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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