Ionic liquids as a Non-conventional Catalyst for the Synthesis of N-heterocycles

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC
Ambika, Pradeep Pratap Singh, Saraswati Kanodia
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引用次数: 0

Abstract

Ionic liquids (ILs) have emerged as one of the potential alternates of organic solvents in chemistry. Nitrogen-containing heterocyclic compounds are the important structural motifs of some bioactive compounds. A variety of ILs such as first-generation, second-generation, and third-generation ILs have been used in the synthesis of various types of nitrogen-containing heterocyclic compounds, such as aziridine, indole, pyrrazole, imidazole, oxazole, thiazole, triazole, pyridine, pyrimidine, quinolones, benzodiazapiene and their derivatives. Due to their unique chemical and physical properties, ILs can act as both solvent and catalyst and have contributed towards high efficiency, improved yield, and recyclability, for the synthesis of heterocyclic skeleton. In this review, the application of ILs in the synthesis of different nitrogen-containing heterocyclic compounds has been discussed.
离子液体作为n-杂环合成的非常规催化剂
离子液体已成为化学中有机溶剂的潜在替代品之一。含氮杂环化合物是一些生物活性化合物的重要结构基序。多种离子液体,如第一代、第二代和第三代离子液体,已用于合成各种类型的含氮杂环化合物,如氮丙啶、吲哚、吡唑、咪唑、恶唑、噻唑、三唑、吡啶、嘧啶、喹诺酮类、苯并二氮杂二烯及其衍生物。由于其独特的化学和物理性质,离子液体既可以作为溶剂又可以作为催化剂,有助于杂环骨架合成的高效率、提高产率和可回收性。本文综述了离子液体在合成不同含氮杂环化合物中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Mini-reviews in Organic Chemistry
Mini-reviews in Organic Chemistry 化学-有机化学
CiteScore
4.50
自引率
4.30%
发文量
116
审稿时长
>12 weeks
期刊介绍: Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges. The journal encourages submission of reviews on emerging fields of organic chemistry including: Bioorganic Chemistry Carbohydrate Chemistry Chemical Biology Chemical Process Research Computational Organic Chemistry Development of Synthetic Methodologies Functional Organic Materials Heterocyclic Chemistry Macromolecular Chemistry Natural Products Isolation And Synthesis New Synthetic Methodology Organic Reactions Organocatalysis Organometallic Chemistry Theoretical Organic Chemistry Polymer Chemistry Stereochemistry Structural Investigations Supramolecular Chemistry
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