Directed synthesis and study of their spectroscopic behavior in solution of rare-earth phthalocyaninates substituted by benzyloxy- and methylphenylethylphenoxy-groups

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2022-01-12 DOI:10.1007/s10847-021-01120-3

A. A. Botnar, A. N. Bychkova, N. P. Domareva, T. V. Tikhomirova, A. S. Vashurin

引用次数: 6

Abstract

Novel neodymium phthalocyaninates based on template condensation of 4-[(4-benzyloxy)phenoxy]- or 4-(1-methyl-1-phenylethyl)phenoxyphthalonitriles with neodymium salts were obtained. The most selective preparation of neodymium sandwich complexes was found to occur with neodymium acetate as a template. The spectroscopic properties of neodymium metal complexes synthesized in organic solvents were studied. It was determined sandwich complexes of neodymium forms a mixture of in "blue" and "green" forms in the solution.

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苯氧基和甲基苯基乙基苯氧基取代稀土酞菁酸酯的定向合成及其在溶液中的光谱行为研究

以4-[(4-苯氧基)苯氧基]-或4-(1-甲基-1-苯乙基)苯氧基酞腈与钕盐为模板缩合剂，制备了新型的邻苯氰酸钕。以醋酸钕为模板制备夹层配合物是最具选择性的。研究了在有机溶剂中合成的金属钕配合物的光谱性质。经测定，在溶液中钕的夹心复合物形成了“蓝色”和“绿色”两种形式的混合物。

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来源期刊

Journal of Inclusion Phenomena and Macrocyclic Chemistry Agricultural and Biological Sciences-Food Science

CiteScore

4.10

自引率

8.70%

发文量

期刊介绍： The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.