Studying the treatment processes of soil samples from radionuclides

K. Mammadov, H. Shiraliyeva, Elnur Ismikhan Mehtiyev, U. Aliyeva-Jabbarly, Elchin Ilham Guliyev, N. Mirzayev, A. Huseynova
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Abstract

Object of research: Soil samples contaminated with radionuclides and processes for treatment of contaminated soil. The problem to be solved: Isolation of radionuclides from contaminated soil samples by extraction with weak solutions of acids and alkalis. Main scientific results: Treatment of soil samples contaminated with uranyl nitrate using extraction with weak solutions of nitric and hydrochloric acid, caustic sodium and subsequent washing of soil residues with distilled water is effective process and leads to a more than tenfold decrease in the content of uranium isotopes (U238, U235, U234 and U236) in the soil samples. At the same time, there is a decrease in the content of natural radionuclides (Na22, K40, Zn65, Sn113, Sn126) in the extracted soil samples. An increase in their content in the extract of the analyzed soil samples corresponds to a decrease in their content in the residue of the extracted soil samples. The analysis of the values of the decrease in the content of natural radionuclides in the soil contaminated with uranyl nitrate corresponds to the values of the decrease in their content in the identical soil, but not contaminated with uranium isotopes. The combined extraction with weak solutions of acids and alkalis leads to the enrichment of the soil with nitrates and chlorine-containing compounds. The area of practical use of the research results: Subdivisions of the Ministry of Emergency Situations and Chemical Troops specializing in the study of emergencies and natural disasters can use the results of these studies in the elimination of the consequences of global environmental disasters and incidents that pose a threat to the life of the civilian population and the personnel of paramilitary units. Innovative technological product: The proposed method for treatment of soil contaminated with radionuclides makes it possible to more than tenfold reduce their concentration in the soil. Scope of application of an innovative technological product: treatment of contaminated soil in areas affected by nuclear tests or accidents at nuclear power plants.
研究放射性核素土壤样品的处理工艺
研究对象:被放射性核素污染的土壤样品和污染土壤的处理过程。要解决的问题是:通过用弱酸和弱碱溶液提取,从受污染的土壤样品中分离放射性核素。主要科学成果:用硝酸、盐酸、苛性钠的弱溶液提取并随后用蒸馏水冲洗土壤残留物,处理被硝酸铀酰污染的土壤样品是一种有效的过程,可使土壤样品中的铀同位素(U238、U235、U234和U236)含量降低十倍以上。同时,提取的土壤样品中天然放射性核素(Na22、K40、Zn65、Sn113、Sn126)的含量有所下降。它们在分析的土壤样品的提取物中含量的增加对应于它们在提取的土壤样品残留物中含量的减少。对被硝酸铀酰污染的土壤中天然放射性核素含量下降值的分析,与未被铀同位素污染的同一土壤中其含量下降值相对应。酸和碱的弱溶液的联合提取导致硝酸盐和含氯化合物富集土壤。研究成果的实际使用领域:紧急情况和化学部专门研究紧急情况和自然灾害的部门可以利用这些研究成果消除全球环境灾害和对平民和准军事部队。创新技术产品:所提出的处理被放射性核素污染的土壤的方法使其在土壤中的浓度降低了十倍以上。创新技术产品的应用范围:处理受核试验或核电站事故影响地区的污染土壤。
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