Pesticide residues in fruits and vegetables in Indonesia: findings of five-year proficiency testing

Abstract

The first proficiency testing of pesticides in fruits and vegetables in Indonesia is reported. This report covers the findings of five-year proficiency testings. Every year, from 2016 to 2020, 18–25 laboratories join the proficiency testings and analyze 5–11 pesticides in tomato, orange, lettuce, brown rice, strawberry respectively. The number of laboratories participating in the proficiency testings tends to increase, although only 38 % of the laboratories are able to report all pesticides. More than 72 % of participants use QuEChERS or its modifications for sample preparation, all participants use gas chromatography or liquid chromatography for separation, at least 20 % of participants still rely on detectors other than mass spectrophotometer for detection, and 20 %–60 % of participants use matrix-matched calibration for quantification. The performance of laboratories is evaluated as z-score with an average of 90.8 % achieves satisfactory results while 3.3 % and 5.9 % achieve questionable and unsatisfactory results correspondingly. Overall, the performance of laboratory participants during proficiency testings is good. However, improvement is still needed, especially for the number of target pesticides for multi-residue pesticide analysis. Moreover, unsatisfactory z-scores are likely to be resulted from laboratories which use conventional solvent extraction, use detectors other than mass spectrometers, and are not accredited.