Facile synthesis of novel interpenetrating polymeric network (IPN) from semi-IPN: comparative analysis of biodegradation studies for environmental remediation

IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED
Anjali Singh, B. Kaith, D. Sud
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引用次数: 0

Abstract

Abstract This paper reports the novel synthesis of an interpenetrating polymer network (IPN) from semi-IPN. This semi-IPN is based on naturally occurring Colocasia esculenta corn starch. The toxicity levels were compared through various biodegradation methods. The polymer network was synthesised from the corresponding semi-IPN via a green pathway by using green solvent (water) and polyvinyl alcohol (PVA) as secondary monomer. The biodegradability of synthesized IPN was tested by vermi-composting, composting and soil burial methods. The study was divided into three stages that lasted up to 70 days. The synthesised IPN degraded 78.94 %, 69.23 % and 67.24 % within 70 days by vermi-composting, composting and burying in the soil, respectively. This was confirmed by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy with electron dispersion analysis (SEM-EDX) for each stage. Therefore, the system could be considered for agrochemical release without affecting soil fertility.
由半互穿网络合成新型互穿聚合物网络:环境修复生物降解研究的比较分析
摘要本文报道了一种由半互穿聚合物网络合成互穿聚合物网络的新方法。这种半ipn是基于天然存在的玉米淀粉。通过不同的生物降解方法比较了其毒性水平。以绿色溶剂(水)和聚乙烯醇(PVA)为二级单体,通过绿色途径合成了相应的半ipn聚合物网络。采用蚯蚓堆肥法、堆肥法和土壤掩埋法对合成的IPN进行了生物降解性试验。研究分为三个阶段,持续70 天。合成的IPN分别通过蚯蚓堆肥、堆肥和埋土在70 天内降解78.94 %、69.23 %和67.24 %。每个阶段的傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM-EDX)证实了这一点。因此,该系统可以考虑在不影响土壤肥力的情况下释放农用化学品。
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来源期刊
Tenside Surfactants Detergents
Tenside Surfactants Detergents 工程技术-工程:化工
CiteScore
1.90
自引率
10.00%
发文量
57
审稿时长
3.8 months
期刊介绍: Tenside Surfactants Detergents offers the most recent results of research and development in all fields of surfactant chemistry, such as: synthesis, analysis, physicochemical properties, new types of surfactants, progress in production processes, application-related problems and environmental behavior. Since 1964 Tenside Surfactants Detergents offers strictly peer-reviewed, high-quality articles by renowned specialists around the world.
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