{"title":"Advancement of Novel Graphene Oxide Embedded Alumina Nickel Composite Coating Developed at Various Current Densities to Evaluate Corrosion Resistance","authors":"U. Pandey, C. Sharma","doi":"10.17807/orbital.v15i1.17525","DOIUrl":null,"url":null,"abstract":"In this research, the influence of deposition current density on the properties of nickel-Graphene oxide/alumina coatings produced by electrodeposition was examined. Nickel matrix composite coatings with graphene oxide doped Alumina (GO-Al2O3) particles were prepared via electrodeposition. When embedding GO-Al2O3 particles in the Ni matrix, remarkable anti-corrosion properties are anticipated due to the outstanding mechanical properties of GO and Al2O3. The structure, content, and morphology of GO, GO-Al2O3, and coatings deposited at various current densities were determined using X-ray diffraction, Fourier transforms infrared spectroscopy, Field emission Scanning electron microscopy, and energy-dispersive X-ray spectroscopy. GO-doped alumina particles were successfully incorporated into the matrix of nickel, according to the findings. Porosity measurement and cross-sectional thickness were also investigated at various current densities. Potentiodynamic polarization testing and electrochemical impedance spectroscopy were used to study the coatings' corrosion-resistant characteristics. According to the findings, coatings developed at high current densities, such as 30 mA cm-2, are porous and not uniform in nature. Furthermore, at high current densities, the content of GO and Alumina is reduced, resulting in a decrease in mechanical and corrosion resistance. Due to its less porous and uniformly formed coating, 10 mA cm-2 was the optimum current density for achieving the most desirable features. \n ","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Orbital: The Electronic Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17807/orbital.v15i1.17525","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
Abstract
In this research, the influence of deposition current density on the properties of nickel-Graphene oxide/alumina coatings produced by electrodeposition was examined. Nickel matrix composite coatings with graphene oxide doped Alumina (GO-Al2O3) particles were prepared via electrodeposition. When embedding GO-Al2O3 particles in the Ni matrix, remarkable anti-corrosion properties are anticipated due to the outstanding mechanical properties of GO and Al2O3. The structure, content, and morphology of GO, GO-Al2O3, and coatings deposited at various current densities were determined using X-ray diffraction, Fourier transforms infrared spectroscopy, Field emission Scanning electron microscopy, and energy-dispersive X-ray spectroscopy. GO-doped alumina particles were successfully incorporated into the matrix of nickel, according to the findings. Porosity measurement and cross-sectional thickness were also investigated at various current densities. Potentiodynamic polarization testing and electrochemical impedance spectroscopy were used to study the coatings' corrosion-resistant characteristics. According to the findings, coatings developed at high current densities, such as 30 mA cm-2, are porous and not uniform in nature. Furthermore, at high current densities, the content of GO and Alumina is reduced, resulting in a decrease in mechanical and corrosion resistance. Due to its less porous and uniformly formed coating, 10 mA cm-2 was the optimum current density for achieving the most desirable features.
本研究考察了沉积电流密度对电沉积镍-氧化石墨烯/氧化铝涂层性能的影响。采用电沉积法制备了氧化石墨烯掺杂氧化铝(GO-Al2O3)颗粒的镍基复合涂层。在Ni基体中嵌入GO-Al2O3颗粒,由于GO和Al2O3优异的力学性能,预期具有显著的抗腐蚀性能。利用x射线衍射、傅里叶变换红外光谱、场发射扫描电子显微镜和能量色散x射线光谱分析了不同电流密度下氧化石墨烯、氧化石墨烯- al2o3和涂层的结构、含量和形貌。根据研究结果,氧化石墨烯掺杂的氧化铝颗粒被成功地结合到镍基体中。孔隙度测量和截面厚度也在不同的电流密度下进行了研究。采用动电位极化测试和电化学阻抗谱技术研究了涂层的耐腐蚀性能。根据研究结果,在高电流密度(如30 mA cm-2)下开发的涂层具有多孔性,并且性质不均匀。此外,在高电流密度下,氧化石墨烯和氧化铝的含量减少,导致机械和耐腐蚀性下降。由于其较少的多孔性和均匀形成的涂层,10 mA cm-2是实现最理想特性的最佳电流密度。
期刊介绍:
Orbital: The Electronic Journal of Chemistry is a quarterly scientific journal published by the Institute of Chemistry of the Universidade Federal de Mato Grosso do Sul, Brazil. Original contributions (in English) are welcome, which focus on all areas of Chemistry and their interfaces with Pharmacy, Biology, and Physics. Neither authors nor readers have to pay fees. The journal has an editorial team of scientists drawn from regions throughout Brazil and world, ensuring high standards for the texts published. The following categories are available for contributions: 1. Full papers 2. Reviews 3. Papers on Education 4. History of Chemistry 5. Short communications 6. Technical notes 7. Letters to the Editor The Orbital journal also publishes a number of special issues in addition to the regular ones. The central objectives of Orbital are threefold: (i) to provide the general scientific community (at regional, Brazilian, and worldwide levels) with a formal channel for the communication and dissemination of the Chemistry-related literature output by publishing original papers based on solid research and by reporting contributions which further knowledge in the field; (ii) to provide the community with open, free access to the full content of the journal, and (iii) to constitute a valuable channel for the dissemination of Chemistry-related investigations.