PHYSICOCHEMICAL AND ANTIOXIDANT PROPERTIES OF HUMIC ACIDS OF LOW-MINERALIZED PELOIDS OF THE TUZKOL DEPOSIT

Zh.К. Кairbekov, I. Jeldybayeva, D.Z. Аbilmazhinova, S. Suimbayeva
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引用次数: 5

Abstract

As a result of studies it was found that the peloids of the deposit of Tuzkol Lake (Republic of Kazakhstan) are high quality medium-sulfide, weakly alkaline sludge muds. It was found that peloid-derived humic acid contains 49.63 % oxygen, 22.37% carbon, 9.65 % silicon and 6.26% calcium; it also contains Na, Mg, Al, Fe and an insignificant amount of S, Cl, K, F. Electron microscopy and IR spectroscopy analysis of the molecular structure of humic substances of peloids indicated that their macromolecule consists of framework olefinic and aromatic fragments with a substantial proportion of unoxidized aliphatic groups, as well as aromatic structures containing carboxyl groups. The findings of amperometric detection of the antioxidant properties of humic acids suggest that they have antioxidant activity, which will make it possible to use them as a biologically active substance for medicines.
TUZKOL矿床低矿化Peloid腐殖酸的理化性质和抗氧化性能
研究发现,图兹科尔湖(哈萨克斯坦共和国)矿床的类球体是优质的中硫化物、弱碱性污泥泥。发现类球衍生腐植酸含氧49.63%、碳22.37%、硅9.65%、钙6.26%;类球体腐殖质分子结构的电镜和红外光谱分析表明,类球体腐殖质大分子由骨架烯烃和芳香片段组成,其中含有相当比例的未氧化脂肪基团,以及含有羧基的芳香结构。对腐植酸抗氧化性能的安培检测结果表明,腐植酸具有抗氧化活性,这将使其有可能作为生物活性物质用于医药。
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