SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF LITHIUM SALTS OF COPPER(II) AND NICKEL(II) COMPLEXES WITH 1,3-PROPANEDIAMINE-N,N,N’,N’-TETRAACETATE

The University Thought - Publication in Natural Sciences Pub Date : 2017-06-18 DOI:10.5937/univtho7-13688

N. Drašković, D. Gurešić

引用次数: 0

Abstract

The complexes Li 2 [Ni(1,3-pdta)]•5H 2 O and Li 2 [Cu(1,3-pdta)]•5H 2 O (where 1,3-pdta represents the 1,3-propanediaminetetraacetate anion) have been synthesized and characterized by applying IR and UV-vis spectroscopy. The obtained spectroscopic results of these complexes are discussed in relation to those for Mg[M(1,3-pdta)].8H 2 O complexes (M = Ni(II) and Cu(II)) of known crystal structure.

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铜（II）和镍（II）与1,3-丙二胺-N，N，N'，N'-四乙酸盐配合物锂盐的合成及光谱表征

合成了Li 2 [Ni(1,3-pdta)]•5h2o和Li 2 [Cu(1,3-pdta)]•5h2o配合物(其中1,3-pdta表示1,3-丙二胺四乙酸阴离子)，并用红外光谱和紫外可见光谱对其进行了表征。讨论了这些配合物的光谱结果与Mg[M(1,3-pdta)]的光谱结果的关系。已知晶体结构的8H 2o配合物(M = Ni(II)和Cu(II))。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

The University Thought - Publication in Natural Sciences

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审稿时长

4 weeks