Convolutive Deconvolutive Voltammetry of Charge Transfer Complexes of 4,4’-Bipyridine With Benzoquinone Derivatives

IF 0.7 4区材料科学 Q4 ELECTROCHEMISTRY

Journal of New Materials For Electrochemical Systems Pub Date : 2021-09-30 DOI:10.14447/jnmes.v24i3.a07

A. Al-Owais, I. El-Hallag, E. El-Mossalamy

引用次数: 0

Abstract

Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.

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4,4'-联吡啶与苯醌衍生物电荷转移配合物的卷积-反卷积伏安法

采用卷积、去卷积循环伏安法、数字模拟、计时电流法、扫描电子显微镜（SEM）和透射电子显微镜（TEM）对4,4’-联吡啶与苯醌衍生物的电荷转移络合物（CT）进行了表征。这些研究是在TBAPL/CH2Cl2中的金电极上完成的。通过上述方法计算和解释了所研究的CT复合物的电极反应类型和动力学参数，然后通过数字模拟进行了确认。进行SEM和TEM以表征所提出的配合物的结构形态以及显示配合物的纳米结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of New Materials For Electrochemical Systems ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

1.90

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： This international Journal is intended for the publication of original work, both analytical and experimental, and of reviews and commercial aspects related to the field of New Materials for Electrochemical Systems. The emphasis will be on research both of a fundamental and an applied nature in various aspects of the development of new materials in electrochemical systems.