{"title":"Crystal Structure of Tertiarybutyl Ammonium Bis[(naphthalene-2,3-diolato)borate] Dimethyl Sulfoxide Solvate","authors":"M. Tombul","doi":"10.2116/xraystruct.35.3","DOIUrl":null,"url":null,"abstract":"Ammonium The structure of tertiarybutyl ammonium bis[naphthalene-2,3-diolato)borate] dimethyl sulfoxide solvate was determined by X-Ray crystallography. The compound crystallized in a triclinic system, and was characterized to be in the space group P -1, with cell parameters a = 9.6282(9)Å, b = 11.0221(9)Å, c = 13.0273(12)Å, α = 91.050(4) 0 , β = 109.419(4) 0 , γ = 94.574(2) 0 , Z = 2, and V = 1298.2(2)Å 3 . The crystal packing is governed by intermolecular and intramolecular N–H···O hydrogen bonds. The B atom takes a distorted tetrahedral geometry with four O atoms of naphthalene-2,3-diolato ligands.","PeriodicalId":23922,"journal":{"name":"X-ray Structure Analysis Online","volume":null,"pages":null},"PeriodicalIF":0.1000,"publicationDate":"2019-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.2116/xraystruct.35.3","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/xraystruct.35.3","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
Ammonium The structure of tertiarybutyl ammonium bis[naphthalene-2,3-diolato)borate] dimethyl sulfoxide solvate was determined by X-Ray crystallography. The compound crystallized in a triclinic system, and was characterized to be in the space group P -1, with cell parameters a = 9.6282(9)Å, b = 11.0221(9)Å, c = 13.0273(12)Å, α = 91.050(4) 0 , β = 109.419(4) 0 , γ = 94.574(2) 0 , Z = 2, and V = 1298.2(2)Å 3 . The crystal packing is governed by intermolecular and intramolecular N–H···O hydrogen bonds. The B atom takes a distorted tetrahedral geometry with four O atoms of naphthalene-2,3-diolato ligands.