Crystal Structure of Tertiarybutyl Ammonium Bis[(naphthalene-2,3-diolato)borate] Dimethyl Sulfoxide Solvate

IF 0.1 Q4 CRYSTALLOGRAPHY
M. Tombul
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引用次数: 0

Abstract

Ammonium The structure of tertiarybutyl ammonium bis[naphthalene-2,3-diolato)borate] dimethyl sulfoxide solvate was determined by X-Ray crystallography. The compound crystallized in a triclinic system, and was characterized to be in the space group P -1, with cell parameters a = 9.6282(9)Å, b = 11.0221(9)Å, c = 13.0273(12)Å, α = 91.050(4) 0 , β = 109.419(4) 0 , γ = 94.574(2) 0 , Z = 2, and V = 1298.2(2)Å 3 . The crystal packing is governed by intermolecular and intramolecular N–H···O hydrogen bonds. The B atom takes a distorted tetrahedral geometry with four O atoms of naphthalene-2,3-diolato ligands.
双[(萘-2,3-二羟基)硼酸叔丁基铵]二甲基亚砜溶剂化物的晶体结构
铵双[萘-2,3-二羟基)硼酸叔丁基铵]二甲基亚砜溶剂合物的结构通过X射线晶体学测定。该化合物在三斜晶系中结晶,并被表征为空间群P-1,细胞参数a=9.6282(9)Å,b=11.0221(9)å,c=13.0273(12)Å、α=91.050(4)0、β=109.419(4)O、γ=94.574(2)0、Z=2和V=1298.2(2)Å3。晶体堆积由分子间和分子内的N–H··O氢键控制。B原子具有畸变的四面体几何结构,具有四个萘-2,3-二羟基配体的O原子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
0.60
自引率
50.00%
发文量
17
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