Michael G. Aberle , James Robertson , Jurian A. Hoogewerff
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引用次数: 1
Abstract
Recently there has been an increase of work dedicated to developing a more objective soil provenancing capability. Notwithstanding the significant progress made, the presented provenancing techniques have predominately been based upon interpolation grids, generated from often arbitrary decisions of the user (e.g., grid cell size, grid placement, interpolation model, etc.). To address the acknowledged reproducibility issues, this paper introduces a spatial modelling technique based upon Voronoi Tessellations that is free from arbitrary user decisions. Termed herein as Voronoi Natural Neighbours Tessellation (VNNT), the proposed approach segments the survey area into many “honeycomb-like” polygons. Of which, the exact number, shape, location, and orientation of polygons are inherently dependent upon the original density of input sampling points from the survey, not a user’s subjective decision.
Utilising compositional geochemistry data from a fit-for-purpose topsoil survey and eleven “blind” soil samples from Canberra, Australia, we compare this proposed VNNT approach against a simpler Voronoi Tessellation, and a previously presented 500 m × 500 m grid following a modified and upscaled Natural Neighbour interpolation. Aside from also being computationally less intensive, our results indicated the proposed VNNT approach regularly yielded at least equal, or often more accurate provenance predictions than that of the gridded Natural Neighbour interpolation. Importantly, the delineation of individual polygons is fundamentally dependent upon the survey’s real sampling design, and most truthfully reflects the underlying sampling density, and associated uncertainties. Consequently, the VNNT approach is significantly less susceptible to expert bias as a result of subjective decision-making and “fine-tuning” of interpolation parameters.
期刊介绍:
Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.