Voronoi Natural Neighbours Tessellation: An interpolation and grid agnostic approach to forensic soil provenancing

IF 2.6 3区 医学 Q2 CHEMISTRY, ANALYTICAL
Michael G. Aberle , James Robertson , Jurian A. Hoogewerff
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引用次数: 1

Abstract

Recently there has been an increase of work dedicated to developing a more objective soil provenancing capability. Notwithstanding the significant progress made, the presented provenancing techniques have predominately been based upon interpolation grids, generated from often arbitrary decisions of the user (e.g., grid cell size, grid placement, interpolation model, etc.). To address the acknowledged reproducibility issues, this paper introduces a spatial modelling technique based upon Voronoi Tessellations that is free from arbitrary user decisions. Termed herein as Voronoi Natural Neighbours Tessellation (VNNT), the proposed approach segments the survey area into many “honeycomb-like” polygons. Of which, the exact number, shape, location, and orientation of polygons are inherently dependent upon the original density of input sampling points from the survey, not a user’s subjective decision.

Utilising compositional geochemistry data from a fit-for-purpose topsoil survey and eleven “blind” soil samples from Canberra, Australia, we compare this proposed VNNT approach against a simpler Voronoi Tessellation, and a previously presented 500 m × 500 m grid following a modified and upscaled Natural Neighbour interpolation. Aside from also being computationally less intensive, our results indicated the proposed VNNT approach regularly yielded at least equal, or often more accurate provenance predictions than that of the gridded Natural Neighbour interpolation. Importantly, the delineation of individual polygons is fundamentally dependent upon the survey’s real sampling design, and most truthfully reflects the underlying sampling density, and associated uncertainties. Consequently, the VNNT approach is significantly less susceptible to expert bias as a result of subjective decision-making and “fine-tuning” of interpolation parameters.

Abstract Image

Voronoi自然邻居镶嵌:一种插值和网格不可知法证土壤溯源方法
最近,致力于发展更客观的土壤溯源能力的工作有所增加。尽管取得了重大进展,但目前提出的证明技术主要基于插值网格,这些网格通常是由用户的任意决定(例如,网格单元大小、网格位置、插值模型等)生成的。为了解决公认的再现性问题,本文介绍了一种基于Voronoi tessellation的空间建模技术,该技术不受任意用户决策的影响。该方法被称为Voronoi自然邻域镶嵌(VNNT),将调查区域分割成许多“蜂窝状”多边形。其中,多边形的确切数量、形状、位置和方向本质上取决于调查输入采样点的原始密度,而不是用户的主观决定。利用来自澳大利亚堪培拉的适合用途的表土调查和11个“blind”土壤样本的成分地球化学数据,我们将提出的VNNT方法与更简单的Voronoi Tessellation方法和先前提出的500 m × 500 m网格进行了比较。除了计算强度较低之外,我们的结果表明,所提出的VNNT方法通常比网格化的自然邻域插值方法产生至少相等或通常更准确的来源预测。重要的是,单个多边形的描绘从根本上依赖于调查的实际抽样设计,并且最真实地反映了潜在的抽样密度和相关的不确定性。因此,由于主观决策和插值参数的“微调”,VNNT方法明显不容易受到专家偏差的影响。
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来源期刊
Forensic Chemistry
Forensic Chemistry CHEMISTRY, ANALYTICAL-
CiteScore
5.70
自引率
14.80%
发文量
65
审稿时长
46 days
期刊介绍: Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.
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