GEOCHEMICAL ANALYSES OF SEEP OILS IN THE SOUTHERN GAFSA BASIN, SW TUNISIA: REASSESSMENT OF REGIONAL HYDROCARBON POTENTIAL

IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY
Kamel Dadi, Riadh Ahmadi, Anis Belhaj Mohamed, Chaouki Khalfi, Najwa Mbarki, Jamel Abdennaceur Ouali
{"title":"GEOCHEMICAL ANALYSES OF SEEP OILS IN THE SOUTHERN GAFSA BASIN, SW TUNISIA: REASSESSMENT OF REGIONAL HYDROCARBON POTENTIAL","authors":"Kamel Dadi,&nbsp;Riadh Ahmadi,&nbsp;Anis Belhaj Mohamed,&nbsp;Chaouki Khalfi,&nbsp;Najwa Mbarki,&nbsp;Jamel Abdennaceur Ouali","doi":"10.1111/jpg.12826","DOIUrl":null,"url":null,"abstract":"<p>The recent discovery of surface oil seeps in the Tamerza area in the west-central Gafsa Basin (southern Tunisia) has prompted a re-evaluation of the hydrocarbon potential of the region. In this paper, we report the results of analyses of seep oils by Rock-Eval pyrolysis (n = 6) and gas chromatography – mass spectrometry (n = 4). The goals of the study were to assess the composition of the seep oils, to investigate the relationship between the seep oils and potential source rocks, and to highlight the significance of the seep oils for oil exploration in the region.</p><p>In the Tamerza area, surface oil seeps have been recorded in numerous formations ranging between the Upper Cretaceous Abiod Limestone Formation and the lower Miocene Sehib Siltstone Formation. The results of this study showed that all the seep oil samples analysed in general had a similar geochemical fingerprint: for example, Pr/Ph values are lower than 1; a plot of Pr/n-C<sub>17</sub> (0.27- 0.36) versus Ph/n-C<sub>18</sub> (0.3-0.8) indicates a marine source rock deposited under reducing anoxic conditions; and Ts/(Ts+Tm) ratios indicate that the source rock was thermally mature. Correlation studies suggest that the oils originated from Cenomanian-Turonian shales corresponding to the informally-named Bahloul equivalent formation. Oil expulsion from this source rock at the seep locations is inferred to have ended by middle Miocene time. However the main phase of folding occurred here in the Pliocene – early Quaternary, and the resulting anticlinal folds are not therefore prospective structural traps for hydrocarbons because they developed after migration had already ceased. Stratigraphic traps and salt structures in the region may be of greater exploration interest.</p><p>A surface oil seep sample was also recovered from the Quaternary upper Segui Formation at Jebel Orbata in the east of the Gafsa Basin. Analysis of this oil sample showed that it has similar geochemical characteristics to the seep oils from the Tamerza area, but that it appears to have had a much more recent migration history. In the eastern Gafsa Basin, Pliocene – early Quaternary anticlinal structures could therefore constitute effective structural traps charged by the same Bahloul equivalent formation source rock.</p>","PeriodicalId":16748,"journal":{"name":"Journal of Petroleum Geology","volume":"45 4","pages":"417-437"},"PeriodicalIF":1.8000,"publicationDate":"2022-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Petroleum Geology","FirstCategoryId":"89","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/jpg.12826","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The recent discovery of surface oil seeps in the Tamerza area in the west-central Gafsa Basin (southern Tunisia) has prompted a re-evaluation of the hydrocarbon potential of the region. In this paper, we report the results of analyses of seep oils by Rock-Eval pyrolysis (n = 6) and gas chromatography – mass spectrometry (n = 4). The goals of the study were to assess the composition of the seep oils, to investigate the relationship between the seep oils and potential source rocks, and to highlight the significance of the seep oils for oil exploration in the region.

In the Tamerza area, surface oil seeps have been recorded in numerous formations ranging between the Upper Cretaceous Abiod Limestone Formation and the lower Miocene Sehib Siltstone Formation. The results of this study showed that all the seep oil samples analysed in general had a similar geochemical fingerprint: for example, Pr/Ph values are lower than 1; a plot of Pr/n-C17 (0.27- 0.36) versus Ph/n-C18 (0.3-0.8) indicates a marine source rock deposited under reducing anoxic conditions; and Ts/(Ts+Tm) ratios indicate that the source rock was thermally mature. Correlation studies suggest that the oils originated from Cenomanian-Turonian shales corresponding to the informally-named Bahloul equivalent formation. Oil expulsion from this source rock at the seep locations is inferred to have ended by middle Miocene time. However the main phase of folding occurred here in the Pliocene – early Quaternary, and the resulting anticlinal folds are not therefore prospective structural traps for hydrocarbons because they developed after migration had already ceased. Stratigraphic traps and salt structures in the region may be of greater exploration interest.

A surface oil seep sample was also recovered from the Quaternary upper Segui Formation at Jebel Orbata in the east of the Gafsa Basin. Analysis of this oil sample showed that it has similar geochemical characteristics to the seep oils from the Tamerza area, but that it appears to have had a much more recent migration history. In the eastern Gafsa Basin, Pliocene – early Quaternary anticlinal structures could therefore constitute effective structural traps charged by the same Bahloul equivalent formation source rock.

突尼斯南部gafsa盆地渗漏油的地球化学分析:区域油气潜力的再评价
最近在Gafsa盆地中西部(突尼斯南部)的Tamerza地区发现了地面石油渗漏,促使人们对该地区的碳氢化合物潜力进行了重新评估。本文报道了6种岩石热解法(n = 6)和4种气相色谱-质谱法(n = 4)对渗漏油的分析结果,目的是评价渗漏油的组成,探讨渗漏油与潜在烃源岩的关系,并强调渗漏油对该地区石油勘探的意义。在Tamerza地区,在上白垩统Abiod灰岩组和下中新统Sehib粉砂岩组之间的许多地层中都记录了地面石油渗漏。研究结果表明,所分析的渗漏油样品具有相似的地球化学指纹图谱:Pr/Ph值均小于1;Pr/n-C17比值(0.27 ~ 0.36)与Ph/n-C18比值(0.3 ~ 0.8)表明海相烃源岩沉积于还原性缺氧条件下;Ts/(Ts+Tm)比值表明烃源岩热成熟。对比研究表明,这些油来自于与非正式名称Bahloul等效地层相对应的Cenomanian-Turonian页岩。据推测,该烃源岩在渗漏部位的排油在中新世中期结束。然而,褶皱的主要阶段发生在上新世-早第四纪,由此产生的背斜褶皱是在运移已经停止后发育的,因此不是有前景的油气构造圈闭。该地区的地层圈闭和盐构造可能具有更大的勘探价值。在Gafsa盆地东部Jebel Orbata地区第四系Segui组上段也获得了地面溢油样品。对该石油样本的分析表明,它与塔默扎地区的渗漏油具有相似的地球化学特征,但它的迁移历史似乎更近。因此,在Gafsa盆地东部,上新世—早第四纪背斜构造可能构成有效的构造圈闭,由相同的Bahloul等效地层烃源岩充能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Petroleum Geology
Journal of Petroleum Geology 地学-地球科学综合
CiteScore
3.40
自引率
11.10%
发文量
22
审稿时长
6 months
期刊介绍: Journal of Petroleum Geology is a quarterly journal devoted to the geology of oil and natural gas. Editorial preference is given to original papers on oilfield regions of the world outside North America and on topics of general application in petroleum exploration and development operations, including geochemical and geophysical studies, basin modelling and reservoir evaluation.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信