An Experimental Study of Propene Reaction of a Laminar Flow Reactor and Validation of its Reduced Mechanism

IF 0.7 Q4 ENGINEERING, MECHANICAL
Cheon Hyeon Cho, Karam Han, C. Sohn, Jeong-sik Han
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引用次数: 0

Abstract

Flow reactors are classified into laminar flow, turbulent flow and jet-stirred reactors depending on flow condition. Laminar flow reactor is a device that measures oxidation process of gaseous fuel and vaporized liquid fuels. Propene oxidation process was observed in a laminar flow reactor with a specified residence time at 6 atm, 968 K, and equivalence ratio of 0.71 and compared with numerical simulations. The Aramco 2.0 chemistry was adopted as a kinetic mechanism which includes 493 species and about 2,700 reaction steps. Oxygen, carbon monoxide, and carbon dioxide concentrations were measured. Numerical results with a time shift of 0.216 s show a good agreement with experimental results. And, a reduced kinetic mechanism was generated and validated based on the Aramco 2.0. The reaction steps are reduced by 23%.
层流反应器丙烯反应的实验研究及其还原机理的验证
流动反应器根据流动条件可分为层流反应器、湍流反应器和射流搅拌反应器。层流反应器是一种测量气体燃料和汽化液体燃料氧化过程的装置。在层流反应器中观察丙烯氧化过程,指定停留时间为6 atm,温度为968 K,等效比为0.71,并进行数值模拟比较。采用Aramco 2.0化学作为动力学机制,包括493种物质,约2700个反应步骤。测量了氧气、一氧化碳和二氧化碳的浓度。计算结果与实验结果吻合较好,时移为0.216 s。基于Aramco 2.0生成并验证了简化的动力学机制。反应步骤减少了23%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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