Drying Behaviour of Al2O3 Inks Containing Carboxymethylcellulose (CMC) for Use in Colloidal Processing

Abstract

One of the most important steps in the extrusion processing of ceramic inks is the initial drying of the ceramic parts. This study aimed to investigate the drying behaviour of an Al2O3-based ceramic ink optimised to be processed by extrusion processing methods, e.g., direct ink writing. Carboxymethylcellulose (CMC) was singly added to a suspension of deionised water and Al2O3 (50:50 wt.%) to perform as a dispersing and plasticising agent. To assess moisture loss as a function of time, the ceramic inks were extruded into two types of polymeric moulds: one with a completely closed profile producing cylindrical samples (disks) and one with an open profile producing ceramic bars. After the injection of the inks, the moulds were exposed to different controlled temperatures (20 and 40 °C) for up to 180 h; moisture loss and warpage were periodically measured, and exponential mathematical expressions (moisture loss × drying time) were obtained. The Al2O3-bars dried for 24 h in open moulds at 20 and 40 °C presented longitudinal warpages of 4.5% and 9%, respectively, while the Al2O3 disks dried in closed moulds presented warpages of 3.5% and 7% in these same temperatures (20 and 40 °C, respectively). The samples were sintered at 1610 °C for 4 h and characterised by scanning electron microscopy (SEM), relative density (Archimedes principle), and X-ray diffraction (XRD), presenting a relative density of 92.3 ± 0.5%, α-Al2O3 as crystalline phase and grain with equiaxed morphology varying between 1 and 5 μm.