Assessment of the effect of straw lignin-based synthetic resin as a modifier on the rheological properties of asphalt binder towards better utilization of straw biomass

Abstract

PurposeTo extend the reuse method and rate of straw biomass, this paper investigated the effect of lignin synthetic phenolic resin (LPF) on the rheological properties of asphalt binder.Design/methodology/approachFour LPFs with 25%, 50%, 75% and 100% substitution rates were prepared by replacing phenol with lignin in synthetic resins and using it as a modifier to prepare a bio-asphalt binder. Temperature sweep tests were conducted to evaluate aging resistance and temperature sensitivity of the bio-asphalt binder. The rutting resistance of the bio-asphalt binder was evaluated by frequency sweeps and multiple stress creep recovery (MSCR) test. Linear amplitude sweep (LAS) tests were conducted to evaluate the fatigue resistance of the bio-asphalt binder. A master curve was constructed to further analyze the rheological properties of the bio-asphalt binder at different frequencies. The low-temperature cracking resistance of the binder was evaluated by G-R parameters, critical temperatures and ΔTc. Fourier transform infrared spectroscopy (FTIR) was performed to investigate the changes in the functional groups of the binder before and after aging.FindingsThe results indicated that adding LPF could improve the high-temperature rutting resistance, fatigue resistance, aging resistance of asphalt and the binders are less affected by temperature. Additionally, LPF slightly prohibited the low-temperature performance of the asphalt binder, which, however, was significantly lower than the base asphalt degradation during aging. Compared with base asphalt binders, the bio-asphalt binder showed no new absorption peaks generated after adding LPF, identifying that the improved asphalt binder performance by LPF was a mainly physical modification.Originality/valueThe main objective of this paper is to further improve the substitution rate (i.e. the mass substitution ratio of lignin to phenol) of lignin and broaden the application of biomass resins, thus realizing resource sustainability.