Amine-Iodine Adducts as Simple but Effective Catalysts for the Synthesis of Organic Carbonates from Epoxides and CO2

IF 2.1 4区化学 Q3 CHEMISTRY, PHYSICAL

Catalysis Surveys from Asia Pub Date : 2021-08-06 DOI:10.1007/s10563-021-09341-9

Biswajit Chowdhury, Anastasia A. Zvinchuk, Rinat R. Aysin, Ekaterina A. Khakina, Polina V. Cherkasova, Sergey E. Lyubimov

引用次数: 5

Abstract

New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO₂ with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions.

Graphic Abstract

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胺碘加合物作为环氧化物和CO2合成有机碳酸盐的简单有效催化剂

将分子碘与便宜的单给胺简单混合制备的新型催化剂，在中等温度(60 ~ 90℃)、中等压力(10 ~ 56 atm)和较低的催化负荷(0.25 ~ 0.5 mol %)下，能有效催化CO2与不同环氧化物的偶联反应。分子体系可以被认为是最简单和最便宜的反应催化剂。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Catalysis Surveys from Asia 化学-物理化学

CiteScore

4.80

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.