Thermal Properties of Acetylated Betung Bamboo (Dendrocalamus asper) Pulp – Polypropylene Biocomposites

Wida Banar Kusumaningrum, Sukma Surya Kusumah, I. Ismadi, R. Rochmadi, Subyakto Subyakto
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Abstract

Thermal properties are important factors to determine the proper manufacturing, processing, and storing of biocomposites. Therefore, the thermal properties of the biocomposite made from acetylated betung bamboo pulp and polypropylene (PP) were investigated. The biocomposite was manufactured by hot pressing at 180 oC for 2 minutes and the fiber contents of the acetylated bamboo pulp used were 10 and 20% according to PP weight. The influence of acetylation and fiber content of bamboo pulp on the thermal properties of the biocomposite were investigated by using differential scanning calorimeter (DSC) and thermogravimetric analyzer (TGA). The results showed that acetylated bamboo pulp-PP biocomposite’s were higher than its pure and untreated biocomposites. The rate of crystallization growth of the acetylated bamboo pulp-PP biocomposites was faster up to 4.5 fold than pure PP composite. In addition, its acetylated bamboo pulp-PP had higher onset and maximum decomposition temperature than its untreated fiber-PP biocomposites but lower than PP. According to the results, the best thermal properties of biocomposite were obtained by acetylation of bamboo pulp with 10% fiber content.   
Betung Bamboo(Dendrocalamus asper)乙酰化纸浆-聚丙烯生物复合材料的热性能
热性能是决定生物复合材料正确制造、加工和储存的重要因素。因此,研究了由乙酰化槟榔竹浆和聚丙烯(PP)制成的生物复合材料的热性能。通过在180℃下热压2分钟来制备生物复合材料,并且所使用的乙酰化竹浆的纤维含量根据PP重量为10%和20%。采用差示扫描量热仪(DSC)和热重分析仪(TGA)研究了竹浆乙酰化和纤维含量对生物复合材料热性能的影响。结果表明,经乙酰化处理的竹浆PP生物复合材料的生物复合性能高于未经处理的纯生物复合材料。乙酰化竹浆-聚丙烯生物复合材料的结晶生长速度比纯聚丙烯复合材料快4.5倍。此外,其乙酰化竹浆PP的起始和最高分解温度高于未处理的纤维PP生物复合材料,但低于PP。结果表明,纤维含量为10%的竹浆乙酰化可获得最佳的生物复合材料热性能。
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