Synthesis and crystal structure of one new cadmium coordination polymer constructed by phenanthroline derivate and 1,4-naphthalenedicarboxylic acid

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Main Group Metal Chemistry Pub Date : 2022-01-01 DOI:10.1515/mgmc-2022-0005

N. Xu, Ming-yue Cui, Yue-Xian Zhang, Limin Chang, Z. Kong, Zhan-lin Xu

引用次数: 1

Abstract

Abstract A cadmium coordination polymer, [Cd(1,4-NDC)(L)] n (1), has been hydrothermally synthesized by using 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) and 1,4-naphthalenedicarboxylic acid (1,4-H2NDC). The complex 1 was characterized by diffraction and elemental analyses. In complex 1, the cadmium ion is distorted octahedral coordinated linking the deprotonated 1,4-NDC anion to form a two-dimensional (2D) layer, and the 2D layer are associated into 3D supramolecular structure via the strong π–π stacking interactions from the conjugated L ligands. In addition, thermogravimetry, powder X-ray diffraction, and the solid-state photoluminescent properties of complex 1 were also studied.

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邻菲咯啉衍生物与1,4-萘二甲酸构建的新型镉配位聚合物的合成及晶体结构

摘要以1-（1H-咪唑并[4,5-f][1,10]菲咯啉-2-基）萘-2-醇（L）和1,4-萘二羧酸（1,4-H2NDC）为原料，水热合成了镉配位聚合物[Cd（1,4-NDC）（L）]n（1）。通过衍射和元素分析对配合物1进行了表征。在配合物1中，镉离子被扭曲的八面体配位连接去质子化的1,4-NDC阴离子，形成二维（2D）层，并且2D层通过共轭L配体的强π–π堆叠相互作用结合成3D超分子结构。此外，还对配合物1的热重分析、粉末X射线衍射和固态光致发光性能进行了研究。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.