Low-temperature preferential CO oxidation in a hydrogen-rich stream over Pt-NaY and modified Pt-NaY catalysts for fuel cell application

Pub Date : 2023-01-10 DOI:10.1002/fuce.202200134
Sachin Malwadkar, Parthasarathi Bera, Chilukuri V. V. Satyanarayana
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Abstract

Preferential oxidation of CO (CO-PROX) in the hydrogen-rich stream has been carried out over Pt-NaY catalysts containing various Pt loadings along with Fe, Co, and Au. Catalysts have been characterized with inductively coupled plasma-atomic emission spectroscopy, Brunauer, Emmett, and Teller surface area, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, temperature programmed reduction, and Pt dispersion. CO-PROX activities and CO oxidation selectivities are observed to increase with an increase in Pt content. Pt-NaY catalyst with 0.75 wt.% Pt loading shows maximum CO-PROX activity at low temperatures. An increase in space velocity decreases the CO and O2 conversions, but CO oxidation selectivity increases. A decrease in activity is observed when reformat gas contains around 20% H2O. During the stability test, no change in CO and O2 conversions is observed, but a small increase in the CO oxidation selectivity is noticed after 10 h indicating that the Pt-NaY catalyst is a promising candidate for CO-PROX reaction in a hydrogen-rich stream. The Pt-Fe-NaY catalyst shows better activity than the Pt-NaY catalyst but starts deactivating after 10 h. However, activity is observed to decrease over Pt-Co-NaY and Pt-Au-NaY catalysts. Pt-Fe-NaY catalyst with 0.75 and 0.35 wt.% Pt and Fe, respectively, shows better CO-PROX activity at a temperature of 75°C.

富氢流中CO的低温优先氧化优于Pt - NaY和改性Pt - NaY催化剂的燃料电池应用
在富氢流中CO (CO - PROX)的优先氧化已经在含有不同Pt负载以及Fe, CO和Au的Pt - NaY催化剂上进行。用电感耦合等离子体原子发射光谱、Brunauer、Emmett和Teller表面积、X射线衍射、透射电子显微镜、X射线光电子能谱、程序升温还原和Pt色散对催化剂进行了表征。CO - PROX活性和CO氧化选择性随Pt含量的增加而增加。Pt - NaY催化剂在低温下表现出最大的CO - PROX活性,Pt负载为0.75 wt.%。空速的增加降低了CO和O2的转化率,但CO的氧化选择性增加。重整气体中H2O含量在20%左右时,活性下降。在稳定性测试中,CO和O2转化率没有变化,但10 h后CO氧化选择性有小幅增加,这表明Pt - NaY催化剂是富氢流中CO - PROX反应的有希望的候选者。Pt - Fe - NaY催化剂表现出比Pt - NaY催化剂更好的活性,但在10 h后开始失活。然而,与Pt - Co - NaY和Pt - Au - NaY催化剂相比,活性有所下降。Pt - Fe - NaY催化剂的Pt含量分别为0.75 wt.%和0.35 wt.%,在温度为75℃时表现出较好的CO - PROX活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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