Diminishing Benefits of Federal Reformulated Gasoline (RFG) Compared to Conventional Gasoline (CG)

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
S. Hoekman, Amber Leland, Gary Bishop
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引用次数: 3

Abstract

The Federal reformulated gasoline (RFG) program originated with the 1990 Clean Air Act Amendments to address high ozone and air toxics levels in major urban areas. These areas include portions of 17 states and represent approximately 30% of the total U.S. gasoline volume. Initially, formulation changes were limited to addition of oxygen and reductions in benzene and fuel Reid vapor pressure (RVP) levels. These reformulations were intended to meet minimum emissions reduction targets for volatile organic compounds (VOCs), air toxics, and oxides of nitrogen (NOx) when compared to a 1990 baseline gasoline in a “1990 technology” vehicle fleet. The United States Environmental Protection Agency (U.S. EPA) developed two computational models, the Simple Model in 1995 and the Complex Model in 1998, for use in demonstrating compliance with the regulations. This article reviews the derivation and evolution of the RFG program. Initially, RFG’s emissions reduction benefits compared to conventional gasoline (CG) resulted primarily from differences in fuel sulfur levels, benzene content, and RVP. However, due to other regulatory changes over the past two decades, the compositions of CG and RFG have nearly converged. Inserting annual average gasoline properties into the Complex Model shows that RFG’s predicted NOx and toxics reduction benefits have largely disappeared, while a VOC reduction benefit persists. This benefit results from CG’s higher summertime vapor pressure, due to the 1 psi RVP increase that is allowed for CG containing 10 vol.% ethanol. Due to fleet turnover and introduction of low-emitting, advanced technology vehicles, fleetwide vehicle emissions have decreased dramatically over the past 20 years. Considering this, along with the general erosion of RFG’s emissions reduction benefits, it is unlikely that RFG provides any demonstrable air quality benefit compared to CG today. RFG’s residual VOC benefit likely could be maintained by application of simpler RVP controls, rather than by continuation of the outdated RFG program. Downloaded from SAE International by Gary Bishop, Thursday, March 07, 2019
与传统汽油(CG)相比,联邦重整汽油(RFG)的效益递减
联邦重新配方汽油(RFG)计划源于1990年《清洁空气法修正案》,旨在解决主要城市地区臭氧和空气毒性水平高的问题。这些地区包括17个州的部分地区,约占美国汽油总量的30%。最初,配方的变化仅限于添加氧气和降低苯和燃料里德蒸汽压(RVP)水平。与“1990年技术”车队中1990年的基准汽油相比,这些重新配方旨在实现挥发性有机化合物(VOCs)、空气毒性物质和氮氧化物(NOx)的最低减排目标。美国环境保护局(U.S.EPA)开发了两个计算模型,即1995年的简单模型和1998年的复杂模型,用于证明符合法规。本文回顾了RFG程序的推导和发展。最初,与传统汽油(CG)相比,RFG的减排效益主要是由于燃料硫含量、苯含量和RVP的差异。然而,由于过去二十年的其他监管变化,CG和RFG的组成几乎趋同。将年平均汽油特性插入复杂模型表明,RFG预测的NOx和有毒物质减少效益已基本消失,而VOC减少效益仍然存在。这种好处是由于CG的夏季蒸汽压较高,这是由于含有10体积%乙醇的CG允许增加1 psi的RVP。由于车队的周转和低排放、先进技术车辆的引入,在过去20年中,快速车辆排放量大幅下降。考虑到这一点,再加上RFG的减排效益普遍受到侵蚀,与今天的CG相比,RFG不太可能提供任何明显的空气质量效益。RFG的剩余VOC效益可能可以通过应用更简单的RVP控制来保持,而不是通过继续使用过时的RFG计划。Gary Bishop于2019年3月7日星期四从SAE International下载
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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