ZnO Polymer Nano Composites Synthesis, Characterization, and Thermo-Mechanical Property Comparison

Q4 Energy
J.C. Chrislin Mario, Y. Christabel Shaji, Y. Brucely, S. Ajith Sinthuja, A. Bovas Herbert Bejaxhin, N. Ramanan
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引用次数: 0

Abstract

Both the polyester resin matrix-based polymer ZnO nano composites and pure polyester sheet were synthesised using the solution casting method. The crystalline structure of the nano-particles was examined inside using X-ray diffraction (XRD). The fundamental polymer composition, additives, organic contaminants, and purity were all assessed by FTIR. A minor alteration in the absorption bands was seen in the polyester system with ZnO added. The thermal properties were examined using differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA), and the results unmistakably demonstrated the creation of a highly cross-linked polyester molecular structure or improved free volume fractions in polymer nano composites. A mechanical analyzer’s tensile and flexural strength tests revealed the potential for nanoparticle aggregation due to a strong interaction with resin. To calculate the relative permittivity and the loss of tangents (tan), dielectric studies had been used. Analysis of the hydrophobic properties of the pure and ZnO polyester nano composite.
ZnO聚合物纳米复合材料的合成、表征及热机械性能比较
采用溶液浇铸法制备了聚酯树脂基聚合物ZnO纳米复合材料和纯聚酯片材。利用x射线衍射(XRD)对纳米颗粒的晶体结构进行了内部检测。聚合物的基本组成、添加剂、有机污染物和纯度都通过FTIR进行了评估。在加入氧化锌的聚酯体系中,吸收带发生了微小的变化。利用差示扫描量热法(DSC)和热重分析(TGA)对热性能进行了检测,结果清楚地表明,聚合物纳米复合材料产生了高度交联的聚酯分子结构或提高了聚合物纳米复合材料的自由体积分数。机械分析仪的拉伸和弯曲强度测试显示,由于与树脂的强烈相互作用,纳米颗粒聚集的潜力。为了计算相对介电常数和切线损耗(tan),使用了介电研究。纯和ZnO聚酯纳米复合材料的疏水性分析。
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来源期刊
Journal of Mines, Metals and Fuels
Journal of Mines, Metals and Fuels Energy-Fuel Technology
CiteScore
0.20
自引率
0.00%
发文量
101
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