The entropy production rate a bridge between thermodynamics and chemical kinetics

Q4 Social Sciences

Revista Mexicana De Fisica E Pub Date : 2022-01-01 DOI:10.31349/revmexfise.19.010212

José Nieto Villar, J. Rieumont, R. Mansilla

引用次数: 0

Abstract

It is shown how through the entropy production rate a natural unification between the formalism of classical thermodynamics and chemical kinetics is achieved. It is also shown how the entropy production rate represents an alternative way to the sensitivity analysis method in order to determine the fundamental steps in a reaction mechanism.

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熵产生率是热力学和化学动力学之间的桥梁

它展示了如何通过熵产率在经典热力学和化学动力学的形式之间实现自然的统一。它还显示了熵产生率如何代表灵敏度分析方法的另一种方法，以确定反应机理中的基本步骤。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Revista Mexicana De Fisica E 社会科学-科学史与科学哲学

CiteScore

0.80

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： The Revista Mexicana de Física (Rev. Mex. Fis.) publishes original papers of interest to our readers from the physical science com unity. Language may be English or Spanish, however, given the nature of our readers, English is recommended. Articles are classified as follows: Research. Articles reporting original results in physical science. Instrumentation. Articles reporting original contributions on design and construction of scientific instruments. They should present new instruments and techniques oriented to physical science problems solutions. They must also report measurements performed with the described instrument. Reviews. Critical surveys of specific physical science topics in which recent published information is analyzed and discussed. They should be accessible to physics graduate students and non specialists, and provide valuable bibliography to the specialist. Comments. Short papers (four pages maximum) that assess critically papers by others authors previously published in the Revista Mexicana de Física. A comment should state clearly to which paper it refers.