Bernardevansite, Al2(Se4+O3)3⋅6H2O, dimorphous with alfredopetrovite and the Al-analogue of mandarinoite, from the El Dragón mine, Potosí, Bolivia

IF 2.8 3区 地球科学 Q2 MINERALOGY
Hexiong Yang, X. Gu, R. Jenkins, R. Gibbs, R. Downs
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引用次数: 0

Abstract

Abstract A new mineral species, bernardevansite (IMA2022-057), ideally Al2(Se4+O3)3⋅6H2O, has been discovered from the El Dragón mine, Potosí Department, Bolivia. It occurs as aggregates or spheres of radiating bladed crystals on a matrix consisting of Co-bearing krut'aite–penroseite. Associated minerals are Co-bearing krut'aite–penroseite, chalcomenite and ‘clinochalcomenite’. Bernardevansite is colourless in transmitted light, transparent with white streak and vitreous lustre. It is brittle and has a Mohs hardness of 2½–3. Cleavage is not observed. The measured and calculated densities are 2.93(5) and 2.997 g/cm3, respectively. Optically, bernardevansite is biaxial (+), with α = 1.642(5), β = 1.686(5) and γ = 1.74(1) (white light). An electron microprobe analysis yielded an empirical formula (based on 15 O apfu) (Al1.26Fe3+0.82)Σ2.08(Se0.98O3)3⋅6H2O, which can be simplified to (Al,Fe3+)2(SeO3)3⋅6H2O. Bernardevansite is the Al-analogue of mandarinoite, Fe3+2(SeO3)3⋅6H2O or dimorphous with P$\bar{6}$2c alfredopetrovite. It is monoclinic, with space group P21/c and unit-cell parameters a = 16.5016(5), b = 7.7703(2), c = 9.8524(3) Å, β = 98.258(3)°, V = 1250.21(6) Å3 and Z = 4. The crystal structure of bernardevansite consists of a corner-sharing framework of M3+O6 (M = Al and Fe) octahedra and Se4+O3 trigonal pyramids, leaving large voids occupied by the H2O groups. There are two unique M3+ positions: M1 is octahedrally coordinated by (4O + 2H2O) and M2 by (5O + H2O). The structure refinement indicates that Al preferentially occupies M1 (= 0.692Al + 0.308Fe) over M2 (= 0.516Al + 0.484Fe). The substitution of the majority of Fe in mandarinoite by Al results in a significant reduction in its unit-cell volume from 1313.4 Å3 to 1250.21(6) Å3 for bernardevansite. The discovery of bernardevansite begs the question whether the Fe3+ end-member, Fe3+2(SeO3)3⋅6H2O, has two polymorphs as well, one with P21/c symmetry, as for mandarinoite and the other P$\bar{6}$2c, as for alfredopetrovite.
玻利维亚波托西El Dragón矿的Bernardevansite,Al2(Se4+O3
摘要:在玻利维亚Potosí省El Dragón矿中发现了一种新的矿物——bernardevansite (IMA2022-057),理想形态为Al2(Se4+O3)3⋅6H2O。它以辐射片状晶体的聚集体或球体的形式出现在含Co-bearing krute - penroseite的基体上。伴生矿物为含铜金榴辉石、辉长石和辉长石。贝纳德文石在透射光下无色,透明,有白色条纹和玻璃光泽。它很脆,莫氏硬度为2½-3。未观察到解理现象。实测密度和计算密度分别为2.93(5)和2.997 g/cm3。光学上,贝纳德褐铁矿为双轴(+),α = 1.642(5), β = 1.686(5), γ = 1.74(1)(白光)。电子探针分析得到经验式(基于15 O apfu) (Al1.26Fe3+0.82)Σ2.08(se0.980 o3)3⋅6H2O,可简化为(Al,Fe3+)2(SeO3)3⋅6H2O。贝纳德橄榄石是al -类似的锰华石,Fe3+2(SeO3)3⋅6H2O或与P$\bar{6}$2c铝辉石二晶相。它是单斜的,空间群P21/c,单位胞参数a = 16.5016(5), b = 7.7703(2), c = 9.8524(3) Å, β = 98.258(3)°,V = 1250.21(6) Å3, Z = 4。贝纳德钒石的晶体结构是由M3+O6 (M = Al和Fe)八面体和Se4+O3三角形金字塔组成的共角框架,留下大的空隙被H2O基团占据。有两个独特的M3+位置:M1由(40o + 2H2O)和M2由(50o + H2O)八面体配位。组织细化表明,Al优先占据M1 (= 0.692Al + 0.308Fe),而M2 (= 0.516Al + 0.484Fe)。Al取代了褐铁矿中的大部分铁,使得褐铁矿的单位胞体积从1313.4 Å3显著减小到1250.21(6)Å3。这一发现提出了一个问题,即Fe3+端元Fe3+2(SeO3)3⋅6H2O是否也具有两种多晶态,一种具有P21/c对称性,与褐铁矿相同,另一种具有P$\bar{6}$2c对称性。
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来源期刊
Mineralogical Magazine
Mineralogical Magazine 地学-矿物学
CiteScore
4.00
自引率
25.90%
发文量
104
审稿时长
6-12 weeks
期刊介绍: Mineralogical Magazine is an international journal of mineral sciences which covers the fields of mineralogy, crystallography, geochemistry, petrology, environmental geology and economic geology. The journal has been published continuously since the founding of the Mineralogical Society of Great Britain and Ireland in 1876 and is a leading journal in its field.
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