The Study of Current-Voltage (I-V) Characteristic Curve of Chitosan-Silver Nanoparticle Composite Membrane

M. Islami, N. N. Rupiasih, M. Sumadiyasa, I. Manuaba
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引用次数: 1

Abstract

A study of the current-voltage (I-V) curve of the chitosan-silver nanoparticle composite membrane (Ch-AgNP) has been conducted. Membranes were prepared by casting method using chitosan as matrix, acetic acid 1% as solvent and silver nanoparticle (AgNP) as filler. AgNP used was 100 ?g. As a comparison is a pure chitosan membrane (membrane Ch). The I-V measurement was performed using a cell model consisting of 2 chambers, chambers 1 and 2. The voltage (V) was measured using Ag/AgCl calomel electrode in electrolyte solution of KCl and CaCl2 with concentration of 0.025 M. All measurements were done at room temperature ± 28 0C. The result shows that in the current range 0.66-0.98 mA, the I-V curve of the Ch-AgNP membrane is ohmic. The conduction value of the composite membrane is smaller than that of the chitosan membrane and the value is greater in the KCl solution than in CaCl2 solution.  
壳聚糖-银纳米粒子复合膜电流-电压特性曲线的研究
研究了壳聚糖-银纳米粒子复合膜的电流-电压(I-V)曲线。以壳聚糖为基质,1%乙酸为溶剂,纳米银(AgNP)为填料,采用流延法制备了膜。使用的AgNP是100?g.作为比较,是纯壳聚糖膜(膜Ch)。I-V测量是使用由2个腔室(腔室1和2)组成的细胞模型进行的。使用Ag/AgCl甘汞电极在浓度为0.025M的KCl和CaCl2电解质溶液中测量电压(V)。所有测量均在室温±28 0C下进行。结果表明,在0.66-0.98mA的电流范围内,Ch-AgNP膜的I-V曲线是欧姆的。复合膜的电导率小于壳聚糖膜的电导率,并且在KCl溶液中的电导率大于在CaCl2溶液中的电导。
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