Production of Zn-doped TiO2 film with enhanced photocatalytic activity

IF 1.9 4区 材料科学 Q3 Materials Science
Tuncay Dikici, Ozan Yılmaz, Alper Akalın, Selim Demirci, Serdar Gültekin, Serdar Yıldırım, Metin Yurddaşkal
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引用次数: 4

Abstract

Abstract

In this study, zinc (Zn)-doped titanium dioxide (TiO2) films were prepared using the two steps: anodic oxidation method and heat treatment process. The crystal structure, morphology and elemental composition of the Zn-doped TiO2 films were investigated. These films were characterized by scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results indicated that the TiO2 films with clear, uniform and short nanopores had a high surface area and high degree of crystallinity. The results showed that the as-anodized TiO2 film was successfully obtained as anatase phase at 450 °C. The results of XPS analysis confirmed the presence of Zn in the lattice of TiO2 as dopant, and thermal diffusion technique was successfully done as doping method. The photocatalytic performances of the Zn-doped TiO2 films were evaluated in terms of their photodegradation rate of methylene blue (MB) in an aqueous solution under UV light irradiation. The results revealed that the Zn-doped TiO2 film had a higher photocatalytic activity in comparison with the undoped sample. This study inspired that Zn-doped TiO2 films are a great potential material to treat wastewater in industrial field.

增强光催化活性的掺锌TiO2薄膜的制备
摘要本研究采用阳极氧化法和热处理两步法制备了锌掺杂二氧化钛(TiO2)薄膜。研究了掺杂锌的TiO2薄膜的晶体结构、形貌和元素组成。利用扫描电子显微镜(SEM)、能谱仪(EDS)、x射线衍射仪(XRD)和x射线光电子能谱仪(XPS)对这些薄膜进行了表征。结果表明,制备的TiO2薄膜具有清晰、均匀、短的纳米孔,具有较高的比表面积和结晶度。结果表明,在450℃的高温下,成功地获得了锐钛矿相的阳极氧化TiO2薄膜。XPS分析结果证实了TiO2晶格中存在Zn作为掺杂剂,并成功采用热扩散技术作为掺杂方法。在紫外光照射下,通过对水溶液中亚甲基蓝(MB)的光降解率来评价锌掺杂TiO2薄膜的光催化性能。结果表明,与未掺杂样品相比,掺杂zn的TiO2薄膜具有更高的光催化活性。本研究启发了锌掺杂TiO2薄膜是一种极具潜力的工业废水处理材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society MATERIALS SCIENCE, CERAMICS-
CiteScore
3.20
自引率
5.30%
发文量
1
审稿时长
>12 weeks
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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