Crystal Structure of Hexakis(quinoline-2-thiolatosilver(I))

Abstract

with ten-micron dimensions were obtained. Single-crystal X-ray diffraction measurements were performed at the SPring-8 BL40XU undulator beamline, and the diffraction intensities were collected by a RIGAKU Saturn-724 CCD detector at 150 K. Crystal data and detailed experimental conditions for diffraction measurements are given in Table 1. The structure The structure of a hexanuclear silver(I) complex with six quinoline-2-thiolato (2-qnt – ) ligands [Ag 6 (C 9 H 6 NS) 6 ] ( 1 ) has been synthesized and characterized. Complex 1 crystallized in a triclinic space group P -1 (No. 2) with a = 8.064(6), b = 13.480(3), c = 13.573(5)Å, α = 113.528(15) ° , β = 104.24(3) ° , γ = 100.46(3) ° , V = 1244.5(11)Å 3 , Z = 1, T = 150 K. The R 1 [ I > 2 σ ( I )] and wR 2(all data) values are 0.032 and 0.089, respectively, for all 4437 independent reflections. The complex has a paddle-wheel-like structure with a trigonally distorted Ag 6 octahedral metal core.