{"title":"Electron Beam-Induced Writing of Nanoscale Iron Wires on a Functional Metal Oxide.","authors":"Florian Vollnhals, Tom Woolcot, Marie-Madeleine Walz, Steffen Seiler, Hans-Peter Steinrück, Geoff Thornton, Hubertus Marbach","doi":"10.1021/jp405640a","DOIUrl":null,"url":null,"abstract":"<p><p>Electron beam-induced surface activation (EBISA) has been used to grow wires of iron on rutile TiO<sub>2</sub>(110)-(1 × 1) in ultrahigh vacuum. The wires have a width down to ∼20 nm and hence have potential utility as interconnects on this dielectric substrate. Wire formation was achieved using an electron beam from a scanning electron microscope to activate the surface, which was subsequently exposed to Fe(CO)<sub>5</sub>. On the basis of scanning tunneling microscopy and Auger electron spectroscopy measurements, the activation mechanism involves electron beam-induced surface reduction and restructuring.</p>","PeriodicalId":520808,"journal":{"name":"The journal of physical chemistry. C, Nanomaterials and interfaces","volume":" ","pages":"17674-17679"},"PeriodicalIF":0.0000,"publicationDate":"2013-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1021/jp405640a","citationCount":"23","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The journal of physical chemistry. C, Nanomaterials and interfaces","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/jp405640a","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2013/8/5 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 23
Abstract
Electron beam-induced surface activation (EBISA) has been used to grow wires of iron on rutile TiO2(110)-(1 × 1) in ultrahigh vacuum. The wires have a width down to ∼20 nm and hence have potential utility as interconnects on this dielectric substrate. Wire formation was achieved using an electron beam from a scanning electron microscope to activate the surface, which was subsequently exposed to Fe(CO)5. On the basis of scanning tunneling microscopy and Auger electron spectroscopy measurements, the activation mechanism involves electron beam-induced surface reduction and restructuring.