Laboratory Detection of Cyanoacetic Acid: A Jet-Cooled Rotational Study.

IF 4.8 2区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS
Miguel Sanz-Novo, Iker León, Elena R Alonso, Lucie Kolesniková, José L Alonso
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引用次数: 0

Abstract

Herein we present a laboratory rotational study of cyanoacetic acid (CH2(CN)C(O)OH), an organic acid as well as a -CN bearing molecule, that is a candidate molecular system to be detected in the interstellar medium (ISM). Our investigation aims to provide direct experimental frequencies of cyanoacetic acid to guide its eventual astronomical search in low-frequency surveys. Using different jet-cooled rotational spectroscopic techniques in the time domain, we have determined a precise set of the relevant rotational spectroscopic constants, including the 14N nuclear quadrupole coupling constants for the two distinct structures, cis- and gauche- cyanoacetic acid. We believe this work will potentially allow the detection of cyanoacetic acid in the interstellar medium, whose rotational features have remained unknown until now.

Abstract Image

Abstract Image

氰乙酸的实验室检测:射流冷却旋转研究。
在这里,我们提出了氰乙酸(CH2(CN)C(O)OH)的实验室旋转研究,它是一种有机酸,也是一种携带-CN的分子,是一种在星际介质(ISM)中检测到的候选分子体系。我们的研究旨在提供氰乙酸的直接实验频率,以指导其最终在低频巡天中进行天文搜索。利用不同的射流冷却旋转光谱技术,我们确定了一组精确的相关旋转光谱常数,包括顺式和间扭式氰基乙酸两种不同结构的14N核四极耦合常数。我们相信这项工作将有可能检测到星际介质中的氰乙酸,其旋转特征到目前为止仍然未知。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Astrophysical Journal
Astrophysical Journal 地学天文-天文与天体物理
CiteScore
8.40
自引率
30.60%
发文量
2854
审稿时长
1 months
期刊介绍: The Astrophysical Journal is the foremost research journal in the world devoted to recent developments, discoveries, and theories in astronomy and astrophysics.
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