Through-space hopping transport in an iodine-doped perylene-based metal–organic framework†

IF 3.2 3区工程技术 Q2 CHEMISTRY, PHYSICAL

Molecular Systems Design & Engineering Pub Date : 2022-07-04 DOI:10.1039/D2ME00108J

Gonçalo Valente, María Esteve-Rochina, Ana Paracana, Antonio Rodríguez-Diéguez, Duane Choquesillo-Lazarte, Enrique Ortí, Joaquín Calbo, Marina Ilkaeva, Luís Mafra, Miguel A. Hernández-Rodríguez, João Rocha, Helena Alves and Manuel Souto

引用次数: 0

Abstract

Electrically conductive Metal-Organic Frameworks (MOFs) have emerged in the past few years as promising materials towards applications in (opto)electronics, electrocatalysis and energy storage, among others. One of the most common...

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掺杂碘的苝基金属-有机骨架中的通过空间跳变输运

导电性金属有机框架(mof)在过去几年中作为光电子、电催化和储能等领域应用的有前途的材料而出现。设计导电mof最常见的策略之一是基于使用电活性有机配体及其部分氧化/还原来增加载流子的数量。虽然苝盐被报道为第一个分子导体，但它们很少被探索作为构建导电mof的基石。本文报道了利用双探针单晶器件在部分配体氧化的情况下，微孔苝基MOF的电导率增强。通过光谱研究和量子化学计算，电导率增强的起源是合理的，支持沿人字形苝填料的穿越空间跳跃传输。本研究为基于苝的导电mof的设计开辟了道路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Molecular Systems Design & Engineering Engineering-Biomedical Engineering

CiteScore

6.40

自引率

2.80%

发文量

144

期刊介绍： Molecular Systems Design & Engineering provides a hub for cutting-edge research into how understanding of molecular properties, behaviour and interactions can be used to design and assemble better materials, systems, and processes to achieve specific functions. These may have applications of technological significance and help address global challenges.