Removal of malachite green from aqueous solution using pulverized teak leaf litter: equilibrium, kinetic and thermodynamic studies.

Q1 Chemistry
Emmanuel O Oyelude, Johannes A M Awudza, Sylvester K Twumasi
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引用次数: 33

Abstract

The removal of malachite green (MG) from aqueous solution using teak leaf litter powder (TLLP) was investigated. The process was influenced by initial concentration, pH and temperature of dye solution as well as TLLP dosage. Optimum removal of MG per gram of TLLP occurred at 2 g/L and at pH 6-8. Dubinin-Radushkevich and Freundlich isotherm models fit the batch adsorption data better than Langmuir isotherm. The monolayer capacity of TLLP was 333.33 mg/g at 293-313 K. The mean free energy of 7.07 kJ/mol implied physical adsorption. The pseudo-second order model fit the kinetic data better than the pseudo-first order model. Both intraparticle diffusion and film diffusion mechanisms jointly influenced the adsorption process but the latter was the rate-controlling step. Thermodynamic data indicated that the process was endothermic, spontaneous and feasible. Therefore, TLLP could be an important low-cost adsorbent for removal of MG from aqueous solution.

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用柚木碎叶从水溶液中去除孔雀石绿:平衡、动力学和热力学研究。
研究了柚木落叶粉(TLLP)对水溶液中孔雀石绿(MG)的去除效果。染料溶液的初始浓度、pH、温度以及TLLP的投加量对该过程均有影响。在2 g/L和pH 6-8时,TLLP的最佳去除率为MG / g。Dubinin-Radushkevich等温线模型和Freundlich等温线模型比Langmuir等温线模型更符合间歇吸附数据。293 ~ 313 K时,TLLP的单层容量为333.33 mg/g。平均自由能为7.07 kJ/mol,表明存在物理吸附。拟二阶模型比拟一阶模型更能拟合动力学数据。颗粒内扩散机制和膜扩散机制共同影响吸附过程,但膜扩散是控制吸附速率的步骤。热力学数据表明,该过程是吸热的、自发的、可行的。因此,TLLP可作为一种重要的低成本吸附剂用于脱除MG水溶液。
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来源期刊
Chemistry Central Journal
Chemistry Central Journal 化学-化学综合
CiteScore
4.40
自引率
0.00%
发文量
0
审稿时长
3.5 months
期刊介绍: BMC Chemistry is an open access, peer reviewed journal that considers all articles in the broad field of chemistry, including research on fundamental concepts, new developments and the application of chemical sciences to broad range of research fields, industry, and other disciplines. It provides an inclusive platform for the dissemination and discussion of chemistry to aid the advancement of all areas of research. Sections: -Analytical Chemistry -Organic Chemistry -Environmental and Energy Chemistry -Agricultural and Food Chemistry -Inorganic Chemistry -Medicinal Chemistry -Physical Chemistry -Materials and Macromolecular Chemistry -Green and Sustainable Chemistry
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