Rational construction of graphitic carbon nitride composited Li-rich Mn-based oxide cathode materials toward high-performance Li-ion battery

Abstract

Li-rich Mn-based oxides (LRMOs) are considered as one of the most-promising cathode materials for next generation Li-ion batteries (LIBs) because of their high energy density. Nevertheless, the intrinsic shortcomings, such as the low first coulomb efficiency, severe capacity/voltage fade, and poor rate performance seriously limit its commercial application in the future. In this work, we construct successfully g-C₃N₄ coating layer to modify Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ (LMNC) via a facile solution. The g-C₃N₄ layer can alleviate the side-reaction between electrolyte and LMNC materials, and improve electronic conduction of LMNC. In addition, the g-C₃N₄ layer can suppress the collapse of structure and improve cyclic stability of LMNC materials. Consequently, g-C₃N₄ (4 wt%)-coated LMNC sample shows the highest initial coulomb efficiency (78.5%), the highest capacity retention ratio (78.8%) and the slightest voltage decay (0.48 V) after 300 loops. Besides, it also can provide high reversible capacity of about 300 and 93 mAh g⁻¹ at 0.1 and 10C, respectively. This work proposes a novel approach to achieve next-generation high-energy density cathode materials, and g-C₃N₄ (4 wt%)-coated LMNC shows an enormous potential as the cathode materials for next generation LIBs with excellent performance.