Jian Zhao , Juan Wang , Aidan J. Brock , Huaiyong Zhu
{"title":"Plasmonic heterogeneous catalysis for organic transformations","authors":"Jian Zhao , Juan Wang , Aidan J. Brock , Huaiyong Zhu","doi":"10.1016/j.jphotochemrev.2022.100539","DOIUrl":null,"url":null,"abstract":"<div><p><span>Plasmonic catalysis has been recognised as a promising alternative to many conventional thermal catalytic processes in organic synthesis. In addition to their high activity in fine chemical synthesis, plasmonic photocatalysts are also able to maintain control of selectivity under mild conditions by utilising visible-light as an energy source. This review provides an overview of the recent advances in organic transformations with plasmonic metal nanostructures<span>, including selective reduction, selective oxidation, cross-coupling and addition reactions. We also summarize the photocatalysts and catalytic mechanisms involving </span></span>surface plasmon resonance. Finally, control of reaction pathway and strategies for tailoring product selectivity in fine chemical synthesis are discussed.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":null,"pages":null},"PeriodicalIF":12.8000,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1389556722000582","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 6
Abstract
Plasmonic catalysis has been recognised as a promising alternative to many conventional thermal catalytic processes in organic synthesis. In addition to their high activity in fine chemical synthesis, plasmonic photocatalysts are also able to maintain control of selectivity under mild conditions by utilising visible-light as an energy source. This review provides an overview of the recent advances in organic transformations with plasmonic metal nanostructures, including selective reduction, selective oxidation, cross-coupling and addition reactions. We also summarize the photocatalysts and catalytic mechanisms involving surface plasmon resonance. Finally, control of reaction pathway and strategies for tailoring product selectivity in fine chemical synthesis are discussed.
期刊介绍：
The Journal of Photochemistry and Photobiology C: Photochemistry Reviews, published by Elsevier, is the official journal of the Japanese Photochemistry Association. It serves as a platform for scientists across various fields of photochemistry to communicate and collaborate, aiming to foster new interdisciplinary research areas. The journal covers a wide scope, including fundamental molecular photochemistry, organic and inorganic photochemistry, photoelectrochemistry, photocatalysis, solar energy conversion, photobiology, and more. It provides a forum for discussing advancements and promoting collaboration in the field of photochemistry.
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