Crystal structure of piperidinium 4-nitro-phenolate.

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-21 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814025306

N Swarna Sowmya, S Sampathkrishnan, S Sudhahar, G Chakkaravarthi, R Mohan Kumar

引用次数: 2

Abstract

In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C-H⋯π inter-actions, forming sheets lying parallel to (001).

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硝基苯酚胡椒啶的晶体结构。

在标题分子盐C5H12N(+)·C6H4NO3(-)中，哌啶环呈椅状构象，阳离子在N原子处质子化。在阴离子中，硝基相对于所附苯环以10.30(11)°的角度扭曲。在晶体中，N-H⋯O氢键将相邻的阴离子和阳离子连接成沿著[100]传播的无限链。这些链由C-H⋯π相互作用连接，形成平行于(001)的薄片。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.