Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa-fluorido-phosphate.

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-12 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814024301

Patrick C Hillesheim, Kent A Scipione

引用次数: 3

Abstract

In the title salt, C11H13N2 (+)·PF6 (-), the dihedral angle between the planes of the imidazole and benzene rings is 84.72 (4)°. In the crystal, C-H⋯F inter-actions connect the cation and anion pairs into a three-dimensional network. Weak π-π inter-actions are observed between the imidazolium ring and the aromatic benzene ring of an adjacent mol-ecule with C⋯C and C⋯N distances ranging from 3.3714 (16) to 3.4389 (15) Å.

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1-苄基-3-甲基- 1h -咪唑六氟磷酸的晶体结构。

在标题盐C11H13N2(+)·PF6(-)中，咪唑环与苯环平面之间的二面角为84.72(4)°。在晶体中，C-H⋯F相互作用将阳离子和阴离子对连接成三维网络。在相邻分子的咪唑环和芳香苯环之间观察到弱π-π相互作用，C⋯C和C⋯N的距离从3.3714(16)到3.4389 (15)Å。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

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